Answer:
This means the amount of PbCrO4 will precipitate first, with a [Pb^2+] concentration of 1.8*10^-12 M
Explanation:
Step 1: Data given
Molarity of Na2CrO4 = 0.010 M
Molarity of NaBr = 2.5 M
Ksp(PbCrO4) = 1.8 * 10^–14
Ksp(PbBr2) = 6.3 * 10^–6
Step 2: The balanced equation
PbCrO4 →Pb^2+ + CrO4^2-
PbBr2 → Pb^2+ + 2Br-
Step 3: Define Ksp
Ksp PbCrO4 = [Pb^2+]*[CrO4^2-]
1.8*10^-14 = [Pb^2+] * 0.010 M
[Pb^2+] = 1.8*10^-14 /0.010
[Pb^2+] = 1.8*10^-12 M
The minimum [Pb^2+] needed to precipitate PbCrO4 is 1.8*10^-12 M
Ksp PbBr2 = [Pb^2+][Br-]²
6.3 * 10^–6 = [Pb^2+] (2.5)²
[Pb^2+] = 1*10^-6 M
The minimum [Pb^2+] needed to precipitate PbBr2 is 1*10^-6 M
This means the amount of PbCrO4 will precipitate first, with a [Pb^2+] concentration of 1.8*10^-12 M
The standard temperature and pressure conditions enthalpy is usually measured under are 1kPa and 273K (option A).
<h3>What is enthalpy?</h3>
Enthalpy in thermodynamics is a measure of the heat content of a chemical or physical system.
Enthalpy is the sum of the internal energy and pressure times volume It can be calculated using the following formula:
H = E + P V
Where;
H = Enthalpy
E = internal energy
P = pressure
V = volume
However, the enthalpy of a substance is usually measured under standard temperature and pressure.
- The standard temperature is 273 Kelvin or K
- The standard pressure is 1kPa
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If the enthalpy is positive and the entropy is positive, the Gibbs energy will always be positive, and the reaction will never be feasible.
<h3>What is the Gibbs Free Energy?</h3>
The Gibb Free Energy is used to obtain the feasibility of a reaction. If the Gibbs free energy is positive the reaction is not spontaneous. If the value is negative, the reaction is spontaneous while a zero values indicates equilibrium.
From the equation;
ΔG = ΔH - TΔS, it follows that if the enthalpy is positive and the entropy is positive, the Gibbs energy will always be positive, and the reaction will never be feasible.
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Answer is: <span>the mass of the excess reactant (ethane) leftover is 90.135 grams.
</span>Chemical reaction: 2C₂H₆(g) + 7O₂(g) → 4CO₂(g) + 6H₂O<span>(g).
m(</span>C₂H₆) = 152 g.
n(C₂H₆) = m(C₂H₆) ÷ M(C₂H₆).
n(C₂H₆) = 152 g ÷ 30 g/mol.
n(C₂H₆) = 5.067 mol.
m(O₂) = 231 g.
n(O₂) = 231 g ÷ 32 g/mol.
n(O₂) = 7.218 mol; limiting reactant.
From chemical reaction: n(O₂) : n(C₂H₆) = 7 : 2.
n(C₂H₆) = 2 · 7.218 mol ÷ 7.
n(C₂H₆) = 2.0625mol.
Δn(C₂H₆) = 5.067 mol - 2.0625 mol.
Δn(C₂H₆) = 3.0045 mol.
Δm(C₂H₆) = 3.0045 mol · 30 g/mol = 90.135 g.
