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ValentinkaMS [17]
3 years ago
8

Can someone help me solve this? I was given the answer at the end of class but I don't understand how the teacher got it. (Direc

tions: Balance each redox reaction in acid solution using the half reaction method.)
PbO2+I2=>Pb^2+ +IO3^- = I2+8H^+ +5PbO2=>2IO3^- +5Pb^+2 +4H2O
Chemistry
1 answer:
KiRa [710]3 years ago
8 0
Unbalanced chemical reaction: PbO₂ + I₂ → Pb²⁺ +IO₃⁻<span>.
First </span><span>determine oxidation numbers of elements:
1) lead on the left side of reaction has oxidation number +4 (x + 2</span>·(-2) = 0) and on the right side +2, so lead is reduced.
2) iodine has neutal charge (0) on left and oxidation number +5 on the right side of chemical reaction (x + 3 · (-2) = -1), so iodine is oxidized.
3) oxygen has oxidation number -2 on both side of chemical reaction.
Second, write balanced half reactions, because this reaction is acidic solution, add hydrogen ions on one side and water on another side of half reaction; balance atoms and electrons on both half reactions:
Half reaction 1: PbO₂ + 4H⁺ + 2e⁻ → Pb²⁺ + 2H₂O /×5
5PbO₂ + 20H⁺ + 10e⁻ → 5Pb²⁺ + 10H₂O.
Half reaction 2: I₂ + 6H₂O → 2IO₃⁻ + 12H⁺ + 10e⁻.
Sum both half reactions and short same ions: 
5PbO₂ + 20H⁺ + I₂ + 6H₂O → 5Pb²⁺ + 10H₂O + 2IO₃⁻ + 12H⁺.
Abbreviate reaction: 5PbO₂ + 8H⁺ + I₂  → 5Pb²⁺ + 4H₂O + 2IO₃⁻..
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See detailed explanation.

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Hello!

i. In this case, since the given chemical reaction is exothermic due to the negative change in the enthalpy of reaction, we infer that according to the mentioned principle, by lowering the temperature the reaction will shift rightwards and therefore the yield is increased; thus, you need a lower temperature than the specified.

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