Answer:
d orbitals
Explanation:
Transition metals are generally known as d-block elements. The electronic configuration of all transition elements finish in a d-orbital weather they are first row, second row or third row transition elements. This is the thread that holds all the elements of the transition series together.
This is why elements of the transition series are generally called the d-block elements.
Answer:
Acetic acid 0,055M and acetate 0,095M.
Explanation:
It is possible to prepare a 0,15M buffer of acetic acid/acetate at pH 5,0 using Henderson-Hasselblach formula, thus:
pH = pka + log₁₀ [A⁻]/[HA] <em>-Where A⁻ is acetate ion and HA is acetic acid-</em>
Replacing:
5,0 = 4,76 + log₁₀ [A⁻]/[HA]
<em>1,7378 = [A⁻]/[HA] </em><em>(1)</em>
As concentration of buffer is 0,15M, it is possible to write:
<em>[A⁻] + [HA] = 0,15M </em><em>(2)</em>
Replacing (1) in (2):
1,7378[HA] + [HA] = 0,15M
2,7378[HA] = 0,15M
[HA] = 0,055M
Thus, [A⁻] = 0,095M
That means you need <em>acetic acid 0,055M</em> and <em>acetate 0,095M</em> to obtain the buffer you need.
i hope it helps!
Answer:

Explanation:
We must do the conversions
mass of C₆H₁₂O₆ ⟶ moles of C₆H₁₂O₆ ⟶ moles of CO₂ ⟶ volume of CO₂
We will need a chemical equation with masses and molar masses, so, let's gather all the information in one place.
Mᵣ: 180.16
C₆H₁₂O₆ + 6O₂ ⟶ 6CO₂ + 6H₂O
m/g: 24.5
(a) Moles of C₆H₁₂O₆

(b) Moles of CO₂

(c) Volume of CO₂
We can use the Ideal Gas Law.
pV = nRT
Data:
p = 0.960 atm
n = 0.8159 mol
T = 37 °C
(i) Convert the temperature to kelvins
T = (37 + 273.15) K= 310.15 K
(ii) Calculate the volume

Answer : The value of
for the reaction is -959.1 kJ
Explanation :
The given balanced chemical reaction is,

First we have to calculate the enthalpy of reaction
.

![\Delta H^o=[n_{H_2O}\times \Delta H_f^0_{(H_2O)}+n_{SO_2}\times \Delta H_f^0_{(SO_2)}]-[n_{H_2S}\times \Delta H_f^0_{(H_2S)}+n_{O_2}\times \Delta H_f^0_{(O_2)}]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo%3D%5Bn_%7BH_2O%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28H_2O%29%7D%2Bn_%7BSO_2%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28SO_2%29%7D%5D-%5Bn_%7BH_2S%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28H_2S%29%7D%2Bn_%7BO_2%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28O_2%29%7D%5D)
where,
= enthalpy of reaction = ?
n = number of moles
= standard enthalpy of formation
Now put all the given values in this expression, we get:
![\Delta H^o=[2mole\times (-242kJ/mol)+2mole\times (-296.8kJ/mol)}]-[2mole\times (-21kJ/mol)+3mole\times (0kJ/mol)]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo%3D%5B2mole%5Ctimes%20%28-242kJ%2Fmol%29%2B2mole%5Ctimes%20%28-296.8kJ%2Fmol%29%7D%5D-%5B2mole%5Ctimes%20%28-21kJ%2Fmol%29%2B3mole%5Ctimes%20%280kJ%2Fmol%29%5D)

conversion used : (1 kJ = 1000 J)
Now we have to calculate the entropy of reaction
.

![\Delta S^o=[n_{H_2O}\times \Delta S_f^0_{(H_2O)}+n_{SO_2}\times \Delta S_f^0_{(SO_2)}]-[n_{H_2S}\times \Delta S_f^0_{(H_2S)}+n_{O_2}\times \Delta S_f^0_{(O_2)}]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo%3D%5Bn_%7BH_2O%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28H_2O%29%7D%2Bn_%7BSO_2%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28SO_2%29%7D%5D-%5Bn_%7BH_2S%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28H_2S%29%7D%2Bn_%7BO_2%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28O_2%29%7D%5D)
where,
= entropy of reaction = ?
n = number of moles
= standard entropy of formation
Now put all the given values in this expression, we get:
![\Delta S^o=[2mole\times (189J/K.mol)+2mole\times (248J/K.mol)}]-[2mole\times (206J/K.mol)+3mole\times (205J/K.mol)]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo%3D%5B2mole%5Ctimes%20%28189J%2FK.mol%29%2B2mole%5Ctimes%20%28248J%2FK.mol%29%7D%5D-%5B2mole%5Ctimes%20%28206J%2FK.mol%29%2B3mole%5Ctimes%20%28205J%2FK.mol%29%5D)

Now we have to calculate the Gibbs free energy of reaction
.
As we know that,

At room temperature, the temperature is 500 K.


Therefore, the value of
for the reaction is -959.1 kJ
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