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atroni [7]
4 years ago
5

When 131.0 mL of water at 26.0°C is mixed with 81.0 mL of water at 85.0°C, what is the final temperature? (Assume that no heat i

s lost to the surroundings; d of water is 1.00 g/mL.)
Chemistry
1 answer:
JulsSmile [24]4 years ago
4 0

Answer:

63.52°C is the final temperature

Explanation:

1) 131.0 mL of water at 26.0°C

Mass of water = m

Volume of the water =131.0 mL

Density of the water = 1.00 g/mL

Density=1.00 g/mL=\frac{m}{131.0 mL}

m = 131.0 g

Initial temperature of the water = T_i = 26.0°C

Final temperature of the water = T_f

Change in temperature ,\Delta T=T_f-T_i

Heat absorbed 131.0 g of water = Q

Q=m\times c\times \Delta T

2) 81.0 mL of water at 85.0°C

Mass of water = m'

Volume of the water =81.0 mL

Density of the water = 1.00 g/mL

Density=1.00 g/mL=\frac{m'}{81.0 mL}

m' = 81.0 g

Initial temperature of the water = T_i' = 85.0°C

Final temperature of the water = T_f'

Change in temperature ,\Delta T'=T_f'-T_i'

Heat lost by 81.0 g of water = Q'

Q'=m'\times c\times \Delta T'

After mixing both liquids the final temperature will become equal fro both liquids.

T_f=T_f'

Since, heat lost by the water at higher temperature will be equal to heat absorbed by the water at lower temperature.

Q=-Q' (Law of conservation of energy.)

Let the specific heat of water be c

m\times c\times \Delta T=m'\times c\times \Delta T'

131.0 g\times c(T_f-26^oC)=-(81.0.0 g\times c(T_f-85^oC))

T_f=63.52^oC

63.52°C is the final temperature

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Q1: 728.6 J.

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<em>Q1: Calculate the energy change (q) of the surroundings (water) using the enthalpy equation:</em>

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where, m is the mass of water (m = d x V = (1.0 g/mL)(24.9 mL) = 24.9 g).

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<em>∴ The amount of heat absorbed by water = Q = m.c.ΔT</em> = (24.9 g)(4.18 J/g°C)(7.0°C) = 728.6 J.

<em>Q2:  Calculate the energy change (q) of the surroundings (water) using the enthalpy equation </em>

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<em>We can assume that the specific heat capacity of water is 4.18 J / (g × °C) and the density of water is 1.00 g/mL. calculate the specific heat of the metal. Use the data from your experiment for the unknown metal in your calculation.</em>

<em></em>

a) First part: the energy change (q) of the surroundings (water):

  • The amount of heat absorbed by water = Q = m.c.ΔT.

where, m is the mass of water (m = d x V = (1.0 g/mL)(25 mL) = 25 g).

c is the specific heat capacity of liquid water = 4.18 J/g°C.

ΔT is the temperature difference = (final T - initial T = 31.6°C - 25.2°C = 6.4°C).

<em>∴ The amount of heat absorbed by water = Q = m.c.ΔT</em> = (25 g)(4.18 J/g°C)(6.4°C) = <em>668.8 J.</em>

<em>b) second part:</em>

<em>Q water = Q unknown metal. </em>

<em>Q unknown metal =  - </em>668.8 J. (negative sign due to the heat is released from the metal to the surrounding water).

<em>Q unknown metal =  - </em>668.8 J = m.c.ΔT.

m = 27.776 g, c = ??? J/g°C, ΔT = (final T - initial T = 31.6°C - 100.5°C = - 68.9°C).

<em>- </em>668.8 J = m.c.ΔT = (27.776 g)(c)( - 68.9°C) = - 1914 c.

∴ c = (<em>- </em>668.8)/(- 1914) = 0.3495 J/g°C.

<em></em>

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