Answer is: ammonia has a higher boiling point because it has stronger intermolecular forces.
Intermolecular forces<span> are the forces between </span><span>molecules. The stronger are intermolecular forces, the higher is boiling point of compound, because more energy is needed to break interaction between molecules.
</span>There are several types of intermolecular forces: hydrogen bonding, i<span>on-induced dipole forces, ion-dipole forces andvan der Waals forces.</span>
1) boiling points increase as molecular weight increase and vice versa. This is due to the increase in van der waals forces between molecules.
2) branching decreases the melting and boiling i.e increase in branching decrease boiling point and melting point. This is due to the fact that there are less point of contact between neighbouring molecules, so molecules are farther apart from each other, which means weaker van der waals(London forces) less energy is required to overcome these force of attraction.
3) In homolytic fission each of the fragment retain one of the bonded electron and radicals are made if the molecule is neutral. In heterolytic fission one fragment gets both bonding electron.
The energy for the heterolytic fission is higher because energy is not only needed to break the covalent bond but also to overcome the force of attraction between oppositely charged ions formed.
Explanation:
Upon dissolution of KCl heat is generated and temperature of the solution raises.
Therefore, heat generated by dissolving 0.25 moles of KCl will be as follows.
= 4.31 kJ
or, = 4310 J (as 1 kJ = 1000 J)
Mass of solution will be the sum of mass of water and mass of KCl.
Mass of Solution = mass of water + (no. of moles of KCl × molar mass)
= 200 g + 
= 200 g + 13.625 g
= 213.625 g
Relation between heat, mass and change in temperature is as follows.
Q = 
where, C = specific heat of water = 
Therefore, putting the given values into the above formula as follows.
Q =
4310 J = 
Thus, we can conclude that rise in temperature will be 
.
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