Answer : The mass of sodium bromide added should be, 18.3 grams.
Explanation :
Molality : It is defined as the number of moles of solute present in kilograms of solvent.
Formula used :

Solute is, NaBr and solvent is, water.
Given:
Molality of NaBr = 0.565 mol/kg
Molar mass of NaBr = 103 g/mole
Mass of water = 315 g
Now put all the given values in the above formula, we get:


Thus, the mass of sodium bromide added should be, 18.3 grams.
Answer:
0.01144L or 1.144x10^-2L
Explanation:
Data obtained from the question include:
V1 (initial volume) = 20.352 mL
P1 (initial pressure) = 680mmHg
P2 (final pressure) = 1210mmHg
V2 (final volume) =.?
Using the Boyle's law equation P1V1 = P2V2, the volume of the container can be obtained as follow:
P1V1 = P2V2
680 x 20.352 = 1210 x V2
Divide both side by 1210
V2 = (680 x 20.352)/1210
V2 = 11.44mL
Now we need to convert 11.44mL to L in order to obtain the desired result. This is illustrated below:
1000mL = 1 L
11.44mL = 11.44/1000 = 0.01144L
Therefore the volume of the container is 0.01144L or 1.144x10^-2L