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Artyom0805 [142]
3 years ago
5

When a container is filled with 3 moles of helium gas, 2 moles of oxygen gas, and 1 mole of carbon dioxide gas, the pressure in

the container is 786 kPa. What is the partial pressure of the oxygen gas?
A. 131 kPa
B. 262 kPa
C. 393 kPa
D. 786 kPa
Chemistry
2 answers:
zhenek [66]3 years ago
8 0
<span>The mole fraction of oxygen gas is 2/6 =1/3, because there are 6 total moles of gas in the container. The partial pressure can be found by multiplying this mole fraction by the total pressure. So the answer is B. 262 kPA because 1/3(786)=262.</span>
Karolina [17]3 years ago
5 0

Answer:

B. 262 kPa

Explanation:

First we must find the total of moles in the container:

3 moles of helium + 2 moles of oxygen + 1 mole s of carbon = 6 moles.

of the total of moles, 2 are oxygen, so the fraction of oxygen in the container is 2/6 = 1/3

Thus, the partial pressure of the oxygen gas must be a third of the total pressure in the container:

Partial pressure of the oxygen gas = \frac{786kPa}{3} = 262 kPa\\

The answer is B. 262 kPa

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Sodium sulfide is the chemical compound with the formula Na2S, or more commonly its hydrate Na2S·9H2O. Both the anhydrous and the hydrated salts are colorless solids. They are water-soluble, giving strongly alkaline solutions. When exposed to moist air, Na2S and its hydrates emit hydrogen sulfide, which smells like rotten eggs. Some commercial samples are specified as Na2S·xH2O, where a weight percentage of Na2S is specified. Commonly available grades have around 60% Na2S by weight, which means that x is around 3. Such technical grades of sodium sulfide have a yellow appearance owing to the presence of polysulfides. These grades of sodium sulfide are marketed as 'sodium sulfide flakes'.

Contents

1 Structure

2 Production

3 Reactions with inorganic reagents

4 Uses

4.1 Reagent in organic chemistry

5 Safety

6 References

Structure

Na2S adopts the antifluorite structure,[2][3] which means that the Na+ centers occupy sites of the fluoride in the CaF2 framework, and the larger S2− occupy the sites for Ca2+.

Production

Industrially Na2S is produced by carbothermic reduction of sodium sulfate often using coal:[4]

Na2SO4 + 2 C → Na2S + 2 CO2

In the laboratory, the salt can be prepared by reduction of sulfur with sodium in anhydrous ammonia, or by sodium in dry THF with a catalytic amount of naphthalene (forming sodium naphthalenide):[5]

2 Na + S → Na2S

Reactions with inorganic reagents

The sulfide ion in sulfide salts such as sodium sulfide can incorporate a proton into the salt by protonation:

S2−

+  H+ → SH−

Because of this capture of the proton ( H+), sodium sulfide has basic character. Sodium sulfide is strongly basic, able to absorb two protons. Its conjugate acid is sodium hydrosulfide (SH−

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S2−

+ H

2O {\displaystyle {\ce {<=>>}}}{\displaystyle {\ce {<=>>}}} SH−

+  OH−

 

 

 

 

(1)

SH−

+ H

2O {\displaystyle {\ce {<<=>}}}{\displaystyle {\ce {<<=>}}} H

2S +  OH−

 

 

 

 

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Sodium sulfide is unstable in the presence of water due to the gradual loss of hydrogen sulfide into the atmosphere.

When heated with oxygen and carbon dioxide, sodium sulfide can oxidize to sodium carbonate and sulfur dioxide:

2 Na2S + 3 O2 + 2 CO

2 → 2 Na2CO3 + 2 SO2

Oxidation with hydrogen peroxide gives sodium sulfate:[6]

Na2S + 4 H2O2 → 4 H

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Reagent in organic chemistry

Alkylation of sodium sulfide give thioethers:

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