0.212 g of KHP is are dissolved in 50.00 mL of water and are titrated by 35.00 mL of 0.0297 M NaOH.
Potassium hydrogen phthalate, KHP, is a monoprotic acid often used to standardize NaOH solutions.
The balanced neutralization equation is:
NaOH(aq) + KHC₈H₄O₄(aq) ⇒ KNaC₈H₄O₄(aq) + H₂O(l)
- Step 1: Calculate the reacting moles of KHP.
0.212 g of KHP react. The molar mass of KHP is 204.22 g/mol.
0.212 g × 1 mol/204.22 g = 1.04 × 10⁻³ mol
- Step 2: Determine the reacting moles of NaOH.
The molar ratio of NaOH to KHP is 1:1.
1.04 × 10⁻³ mol KHP × 1 mol NaOH/1 mol KHP = 1.04 × 10⁻³ mol NaOH
- Step 3: Calculate the molarity of NaOH.
1.04 × 10⁻³ moles of NaOH are in 35.00 mL of solution.
[NaOH] = 1.04 × 10⁻³ mol / 35.00 × 10⁻³ L = 0.0297 M
0.212 g of KHP is are dissolved in 50.00 mL of water and are titrated by 35.00 mL of 0.0297 M NaOH.
Learn more about titration here: brainly.com/question/4225093
about 43001 is it i think
Complete Question
You determine that it takes 26.0 mL of base to neutralize a sample of your unknown acid solution. The pH of the solution was 7.82 when exactly 13 mL of base had been added, you notice that the concentration of the unknown acid was 0.1 M. What is the pKa of your unknown acid?
Answer:
The pK_a value is 
Explanation:
From the question we are told
The volume of base is 
The pH of solution is 
The concentration of the acid is 
From the pH we can see that the titration is between a strong base and a weak acid
Let assume that the the volume of acid is 
Generally the concentration of base
Substituting value
When 13mL of the base is added a buffer is formed
The chemical equation of the reaction is
Now before the reaction the number of mole of base is
![No \ of \ moles[N_B] = C_B * V_B](https://tex.z-dn.net/?f=No%20%5C%20of%20%5C%20moles%5BN_B%5D%20%20%3D%20%20C_B%20%2A%20V_B)
Substituting value
Now before the reaction the number of mole of acid is
Substituting value
Now after the reaction the number of moles of base is zero i.e has been used up
this mathematically represented as
The number of moles of acid is
The pH of this reaction can be mathematically represented as
![pH = pK_a + log \frac{[base]}{[acid]}](https://tex.z-dn.net/?f=pH%20%20%3D%20pK_a%20%2B%20log%20%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D)
Substituting values
DE = dH - PdV
<span>2 H2O(g) → 2 H2(g) + O2(g) </span>
<span>You can see that there are 2 moles of gas in the reactants and 3 moles of gas in the products. </span>
<span>1 moles of ideal gas occupies the same volume as 1 mole of any other ideal gas under the same conditions of temp and pressure. </span>
<span>Since it is done under constant temp and pressure that means the volume change will be equal to the volume of 1 mole of gas </span>
<span>2 moles reacts to form 3 moles </span>
<span>The gas equation is </span>
<span>PV = nRT </span>
<span>P = pressure </span>
<span>V = volume (unknown) </span>
<span>n = moles (1) </span>
<span>R = gas constant = 8.314 J K^-1 mol^-1 </span>
<span>- the gas constant is different for different units of temp and pressure (see wikki link) in this case temp and pressure are constant, and we want to put the result in an equation that has Joules in it, so we select 8.314 JK^-1mol^-1) </span>
<span>T = temp in Kelvin (kelvin = deg C + 273.15 </span>
<span>So T = 403.15 K </span>
<span>Now, you can see that PV is on one side of the equation, and we are looking to put PdV in our dE equation. So we can say </span>
<span>dE = dH -dnRT (because PV = nRT) </span>
<span>Also, since the gas constant is in the unit of Joules, we need to convert dH to Joules </span>
<span>dH = 483.6 kJ/mol = 483600 Joules/mol </span>
<span>dE = 483600 J/mol - (1.0 mol x 8.314 J mol^-1K-1 x 403.15 K) </span>
<span>dE = 483600 J/mol - 3351.77 J </span>
<span>dE = 480248.23 J/mol </span>
<span>dE = 480.2 kJ/mol </span>
