Knowledge of atomic structure has evolved over time. Thomson discovered that atoms contain electrons, Rutherford discovered that
2 answers:
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Explanation:
As per the Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.
Hence, according to this law the chemical equation can be treated as ordinary algebraic expression and can be added or subtracted to yield the required equation. This means that the enthalpy change of the overall reaction is the sum of the enthalpy changes of the intermediate reactions.
..........(1)
..............(2)
The final reaction is as follows:
.............(3)
Therefore, adding (1) and (2) we get the final equation (3) and value of at 298 K will be as follows.
=
+
= -314 kJ + (-80) kJ
= -394 kJ
Thus, we can conclude that at 298 K for the given process is -394 kJ.
Answer:
II
Explanation:
We must have a good idea of the fact that there are two mechanisms that come into play when we are discussing about the addition of hydrogen halides to alkenes. The first is the ionic mechanism and the second is the radical mechanism.
The ionic mechanism is accounted for by the Markovnikov rule while the radical mechanism occurs in the presence of peroxides and is generally referred to as anti Markovnikov addition.
The intermediate in anti Markovnikov addition involves the most stable radical, in this case, it is a tertiary radical as shown in the images attached. The most stable radical is II hence it leads to the major product shown in the other image.
