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g100num [7]
3 years ago
13

Consider a balloon that has a volume V. It contains n moles of gas, it has an internal pressure of P, and its temperature is T.

If the balloon is heated to a temperature of 15.5T while it is placed under a high pressure of 15.5P, how does the volume of the balloon change?
Chemistry
2 answers:
Dmitry [639]3 years ago
6 0
B.) it stays the same
eduard3 years ago
4 0

Answer: The temperature will not change and will remain T.

Explanation: Accoding to ideal gas law:

PV=nRT

where,

P = pressure of the gas

V = volume of the gas

T = temperature of the gas

n = number of moles of gas

R = Gas constant = 0.0821 Latm/moleK

\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}

P_1= initial pressure

V_1= initial volume

T_1= initial temperature

P_2= final pressure

V_2= final volume

T_2= final temperature

Putting in the values:

\frac{PV}{T}=\frac{15.5PV_2}{15.5T}

T_2=T

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Kp = 0.022

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<em>Full question: ...With 2.3 atm of ammonia gas at 32. °C. He then raises the temperature, and when the mixture has come to equilibrium measures the partial pressure of hydrogen gas to be 0.69 atm. </em>

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The equilibrium of ammonia occurs as follows:

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Kp = \frac{P_{N_2}P_{H_2}^3}{P_{NH_3}^2}

<em>Where P represents partial pressure of each gas.</em>

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As initial pressure of ammonia is 2.3atm, its equilibrium concentration will be:

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Consider the reaction given below.
Drupady [299]

Answer:

  • <u>K =  0.167 s⁻¹</u>

Explanation:

<u>1) Rate law, at a given temperature:</u>

  • Since all the data are obtained at the same temperature, the equilibrium constant is the same.

  • Since only reactants A and B participate in the reaction, you assume that the form of the rate law is:

        r = K [A]ᵃ [B]ᵇ

<u>2) Use the data from the table</u>

  • Since the first and second set of data have the same concentration of the reactant A, you can use them to find the exponent b:

        r₁ = (1.50)ᵃ (1.50)ᵇ = 2.50 × 10⁻¹ M/s

        r₂ = (1.50)ᵃ (2.50)ᵇ = 2.50 × 10⁻¹ M/s

         Divide r₂ by r₁:     [ 2.50 / 1.50] ᵇ = 1 ⇒ b = 0

  • Use the first and second set of data to find the exponent a:

        r₁ = (1.50)ᵃ (1.50)ᵇ = 2.50 × 10⁻¹ M/s

        r₃ = (3.00)ᵃ (1.50)ᵇ = 5.00 × 10⁻¹ M/s

        Divide r₃ by r₂: [3.00 / 1.50]ᵃ = [5.00 / 2.50]

                                  2ᵃ = 2 ⇒ a = 1

         

<u>3) Write the rate law</u>

  • r = K [A]¹ [B]⁰ = K[A]

This means, that the rate is independent of reactant B and is of first order respect reactant A.

<u>4) Use any set of data to find K</u>

With the first set of data

  • r = K (1.50 M) = 2.50 × 10⁻¹ M/s ⇒ K = 0.250 M/s / 1.50 M = 0.167 s⁻¹

Result: the rate constant is K =  0.167 s⁻¹

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