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lorasvet [3.4K]
3 years ago
11

Which substance is liquid at 0°C? 1. alcohol 2. aluminum 3. ammonia 4. copper

Chemistry
1 answer:
Tanya [424]3 years ago
5 0
Alcohol, alcohol is the only liquid  since copper and aluminum are a solid ammonia is a bacteria
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A solution contains 0.0440 M Ca2 and 0.0940 M Ag. If solid Na3PO4 is added to this mixture, which of the phosphate species would
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C. Ca_3(PO_4)_2  will precipitate out first

the percentage of Ca^{2+}remaining =  12.86%

Explanation:

Given that:

A solution contains:

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[Ag^+] = 0.0940 \ M

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Thus;

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replacing the known values in order to determine the unknown ; we have :

8.89 \times 10 ^{-17}  = (0.0940)^3[PO_4^{3-}]

\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3}  = [PO_4^{3-}]

[PO_4^{3-}] =\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3}

[PO_4^{3-}] =1.07 \times 10^{-13}

The dissociation  of Ca_3(PO_4)_2

The solubility product constant of Ca_3(PO_4)_2  is 2.07 \times 10^{-32}

The dissociation of Ca_3(PO_4)_2   is :

Ca_3(PO_4)_2 \to 3Ca^{2+} + 2 PO_{4}^{3-}

Thus;

Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2

2.07 \times 10^{-33} = (0.0440)^3  [PO_4^{3-}]^2

\dfrac{2.07 \times 10^{-33} }{(0.0440)^3}=   [PO_4^{3-}]^2

[PO_4^{3-}]^2 = \dfrac{2.07 \times 10^{-33} }{(0.0440)^3}

[PO_4^{3-}]^2 = 2.43 \times 10^{-29}

[PO_4^{3-}] = \sqrt{2.43 \times 10^{-29}

[PO_4^{3-}] =4.93 \times 10^{-15}

Thus; the phosphate anion needed for precipitation is smaller i.e 4.93 \times 10^{-15} in Ca_3(PO_4)_2 than  in  Ag_3PO_4  1.07 \times 10^{-13}

Therefore:

Ca_3(PO_4)_2  will precipitate out first

To determine the concentration of [Ca^+] when  the second cation starts to precipitate ; we have :

Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2

2.07 \times 10^{-33}  = [Ca^{2+}]^3 (1.07 \times 10^{-13})^2

[Ca^{2+}]^3 =  \dfrac{2.07 \times 10^{-33} }{(1.07 \times 10^{-13})^2}

[Ca^{2+}]^3 =1.808 \times 10^{-7}

[Ca^{2+}] =\sqrt[3]{1.808 \times 10^{-7}}

[Ca^{2+}] =0.00566

This implies that when the second  cation starts to precipitate ; the  concentration of [Ca^{2+}] in the solution is  0.00566

Therefore;

the percentage of Ca^{2+}  remaining = concentration remaining/initial concentration × 100%

the percentage of Ca^{2+} remaining = 0.00566/0.0440  × 100%

the percentage of Ca^{2+} remaining = 0.1286 × 100%

the percentage of Ca^{2+}remaining =  12.86%

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