Answer: (a) K *[A][B]^2
(b) The answer is B
Explanation:
A)
Step1:A+B<--> C (fast)
Step2: B+C→D(slow)
Rate depends on slowest step.
so,
rate = k' [B][C] ...eqn 1
But C is intermediate.so use step 1
Since 1st step is an equilibrium,
Kc = [C] /[A][B]
so,
[C] = Kc [A][B] ...eqn 2
put eqn 2 in eqn 1
rate = k' *[B] * Kc [A][B]
= k'Kc*[A][B]^2
= K *[A][B]^2 {writing k'Kc = K}
Answer: K *[A][B]^2
B)
Answer is B
Since rate depends on slowest step.
if slowest step is:
X2Y2+Z2→X2Y2Z+Z
then only,
rate= k[X2Y2][Z2]
Answer: B
find mol of N2 present using gas law equation
PV = nRT
P = pressure = 688/760 = 0.905 atm.
V = 100mL = 0.1L
n = ???
R = 0.082057
T = 565+273 = 838
Substitute:
0.905*0.1 = n*0.082057*838
n = 0.0905 / 68.76
n = 0.00132 mol N2
Molar mass N2 = 28 g/mol
0.00132 mol = 0.00132*28 = 0.037g N2 gas
Think it would be distillation
Answer:
...................................................
Answer:
0.109 g.
Explanation:
Equation of the reaction:
Na3PO4 + 3HCl --> 3NaCl + H3PO4
Number of moles of HCl = molar concentration × volume
= 0.1 × 0.04
= 0.004 mol.
By stoichiometry, 1 mole of Na3PO4 neutralises 3 moles of HCl. Therefore, number of moles of Na3PO4 = 0.004/3
= 0.0013 mol
Mass of Na3PO4 = molar mass × number of moles
= 0.0013 × 164
= 0.219 g
Since 50% of Na3PO4 was present in the sample. Let 100 g be the total mass of the substance
= 0.219 × 50 g/100 g
= 0.109 g.