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Murrr4er [49]
3 years ago
15

Element Y has two naturally occurring isotopes. The most dominant isotope has a mass of 114.3789 amu and a percent abundance of

64.23%. What is
the mass of the second isoptope if the average atomic mass is 128.4359 amu? Remember that the two percentages will have to sum to 100%.
Answer to the correct number of sigtigs including units in your answer.
(to receive full credit, work must be submitted for this question)
Chemistry
1 answer:
olga2289 [7]3 years ago
5 0

Answer:

153.6771 amu

Explanation:

From the question given above, the following data were:

Isotope A:

Mass of A = 114.3789 amu

Abundance (A%) = 64.23%

Isotope B:

Mass of B =.?

Abundance (B%) = 100 – A%

Abundance (B%) = 100 – 64.23

Abundance (B%) = 35.77%

average atomic mass of Element Y = 128.4359 amu

The mass of the 2nd isotope (i.e isotope B) can be obtained as follow:

Average atomic mass = [(Mass of A × A%)/100] + [(Mass of B × B%)/100]

128.4359 = [(114.3789 × 64.23)/100] + [(Mass of B × 35.77) /100]

128.4359 = 73.4656 + (Mass of B × 0.3577)

Collect like terms

128.4359 – 73.4656 = Mass of B × 0.3577

54.9703 = Mass of B × 0.3577

Divide both side by 0.3577

Mass of B = 54.9703 / 0.3577

Mass of B = 153.6771 amu

Therefore, the mass of the 2nd isotope is 153.6771 amu

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What must be the molarity of an aqueous solution of trimethylamine, (ch3)3n, if it has a ph = 11.20? (ch3)3n+h2o⇌(ch3)3nh++oh−kb
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<h3>Explanation</h3>

(\text{CH}_3)_3\text{N} in this question acts as a weak base. As seen in the equation in the question, (\text{CH}_3)_3\text{N} produces \text{OH}^{-} rather than \text{H}^{+} when it dissolves in water. The concentration of \text{OH}^{-} will likely be more useful than that of \text{H}^{+} for the calculations here.

Finding the value of [\text{OH}^{-}] from pH:

Assume that \text{pK}_w = 14,

\begin{array}{ll}\text{pOH} = \text{pK}_w - \text{pH} \\ \phantom{\text{pOH}} = 14 - 11.20 &\text{True only under room temperature where }\text{pK}_w = 14 \\\phantom{\text{pOH}}= 2.80\end{array}.

[\text{OH}^{-}] =10^{-\text{pOH}} =10^{-2.80} = 1.59\;\text{mol}\cdot\text{dm}^{-3}.

Solve for [(\text{CH}_3)_3\text{N}]_\text{initial}:

\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{[(\text{CH}_3)_3\text{N}]_\text{equilibrium}} = \text{K}_b = 1.58\times 10^{-3}

Note that water isn't part of this expression.

The value of Kb is quite small. The change in (\text{CH}_3)_3\text{N} is nearly negligible once it dissolves. In other words,

[(\text{CH}_3)_3\text{N}]_\text{initial} = [(\text{CH}_3)_3\text{N}]_\text{final}.

Also, for each mole of \text{OH}^{-} produced, one mole of (\text{CH}_3)_3\text{NH}^{+} was also produced. The solution started with a small amount of either species. As a result,

[(\text{CH}_3)_3\text{NH}^{+}] = [\text{OH}^{-}] = 10^{-2.80} = 1.58\times 10^{-3}\;\text{mol}\cdot\text{dm}^{-3}.

\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{[(\text{CH}_3)_3\text{N}]_\textbf{initial}} = \text{K}_b = 1.58\times 10^{-3},

[(\text{CH}_3)_3\text{N}]_\textbf{initial} =\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{\text{K}_b},

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