Components in a mixture don’t chemically react while compounds do chemically react and some of their original properties may be lost. A solution is when the solute mixed with the solvent.
Answer:
B = b -a/RT
C = b^2
a = 1.263 atm*L^2/mol^2
b = 0.03464 L/mol
Explanation:
In the given question, we need to express the van der Waals equation of state as a virial expansion in powers of 1/Vm and obtain expressions for B and C in terms of the parameters a and b. Therefore:
Using the van deer Waals equation of state:
With further simplification, we have:
Then, we have:
Therefore,
Using the expansion:
Therefore,
Thus:
equation (1)
Using the virial equation of state:
Thus:
equation (2)
Comparing equations (1) and (2), we have:
B = b -a/RT
C = b^2
Using the measurements on argon gave B = −21.7 cm3 mol−1 and C = 1200 cm6 mol−2 for the virial coefficients at 273 K.
[/tex] = 0.03464 L/mol
a = (b-B)*RT = (34.64+21.7)*(1L/1000cm^3)*(0.0821)*(273) = 1.263 atm*L^2/mol^2
can you zoom in a bit more
1, When temperature is increased the volume will also increase. this is because the particles will gain kinetic energy and bombard the walls of the container of the gas at a higher frequency, therefore, for the pressure to remain constant as per Charles' law, the volume will have to increase so that the rate of bombardment remains constant. This is explained by the Charles law which states that the volume of a gas is directly proportional to the absolute temperature provided pressure remains constant.
2. When temperature is Decreased the volume will also Decrease. this is because the particles will loose kinetic energy and bombard the walls of the container of the gas less frequently, therefore, for the pressure to remain constant as per Charles' law, the volume will have to reduce so that the rate of bombardment remains constant. This is explained by the Charles law which states that the volume of a gas is directly proportional to the absolute temperature provided pressure remains constant.
3. When temperature is increased the pressure will increase. This is because the gas particles gain kinetic energy and bombard the walls of the container more frequently. this is according to Pressure law which states that for a constant volume of a gas the pressure is directly proportional to absolute temperature
4. When temperature is decreased, pressure will decrease, This is because the gas particles lose kinetic energy and bombard the walls of the container less frequently. this is according to Pressure law which states that for a constant volume of a gas the pressure is directly proportional to absolute temperature
5. When particles are added, pressure will increase. This is because the bombardment per unit area also increases. Boyles law explains this, that at fixed temperature the volume of a gas is inversely proportional to the pressure.
6. When particles are removed, the pressure will decrease. This is because the bombardment per unit area also decreases. Boyle's law explains this, that at fixed temperature the volume of a gas is inversely proportional to the pressure.