As we move down the group, the metallic bond becomes more stable and the formation of forming covalent bond decreases down the group due to the large size of elements.
Covalent and metallic bonding leads to higher melting points. Due to a decrease in attractive forces from carbon to lead there is a drop in melting point.
Carbon forms large covalent molecules than silicon and hence has a higher melting point than silicon.
Similarly, Ge also forms a large number of covalent bonds and has a smaller size as compared to that of Sn. Hence melting point decreases from Ge to Sn.
The order will be C>Si>Ge>Pb>Sn.
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Answer:
1. pH = 1.23.
2. 
Explanation:
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1. In this case, for the ionization of H2C2O4, we can write:

It means, that if it is forming a buffer solution with its conjugate base in the form of KHC2O4, we can compute the pH based on the Henderson-Hasselbach equation:
![pH=pKa+log(\frac{[base]}{[acid]} )](https://tex.z-dn.net/?f=pH%3DpKa%2Blog%28%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D%20%29)
Whereas the pKa is:

The concentration of the base is 0.347 M and the concentration of the acid is 0.347 M as well, as seen on the statement; thus, the pH is:

2. Now, since the addition of KOH directly consumes 0.070 moles of acid, we can compute the remaining moles as follows:

It means that the acid remains in excess yet more base is yielded due to the effect of the OH ions provided by the KOH; therefore, the undergone chemical reaction is:

Which is also shown in net ionic notation.
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Answer:
<em>K</em><em>+</em><em>Cl</em><em /><em>KCl</em>
Explanation:
because the reaction is between metal Potassium and Non-metal Chlorine
<span>Ultrafiltration is a process which prevents the dilution of the bloos. During this process some of water with some dissolved materials is forced </span>through the membrane by maintaining the blood at a higher pressure than the solution.