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Hatshy [7]
3 years ago
5

A smaple of 1cm cuvette gives an absorbance reading of 0.558. if they absorptivity for this sample is 15000l/(mol.cm), what is t

he molar concentration
Chemistry
1 answer:
Mazyrski [523]3 years ago
3 0
To solve this problem, we use Beer's Law: A= ε.l.c
A is the absorbance- 0,558
<span>ε is</span> the molar absorptivity- is <span>15000 </span><span><span>L⋅mol-1</span><span>cm-1</span></span>
<span>l is </span>the length of the cuvette- 1 cm
<span>c is</span> the molar concentration

Applying the formula,
0,558= 15000 x 1 x c
0,558/15000= c
c= <span>3.72×<span>10⁻⁵ </span> <span>mol⋅L<span>⁻¹</span></span></span>
<span />
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Calculate the pH at the equivalence point for the titration of 0.110 M methylamine (CH3NH2) with 0.110 M HCl. The Kb of methylam
nikklg [1K]
The reaction between the reactants would be:

CH₃NH₂ + HCl ↔ CH₃NH₃⁺ + Cl⁻

Let the conjugate acid undergo hydrolysis. Then, apply the ICE approach.

             CH₃NH₃⁺ + H₂O → H₃O⁺ + CH₃NH₂
I                0.11                       0             0
C               -x                          +x           +x
E            0.11 - x                     x             x

Ka = [H₃O⁺][CH₃NH₂]/[CH₃NH₃⁺]

Since the given information is Kb, let's find Ka in terms of Kb.

Ka = Kw/Kb, where Kw = 10⁻¹⁴

So,
Ka = 10⁻¹⁴/5×10⁻⁴ = 2×10⁻¹¹ = [H₃O⁺][CH₃NH₂]/[CH₃NH₃⁺]
2×10⁻¹¹ = [x][x]/[0.11-x]
Solving for x,
x = 1.483×10⁻⁶ = [H₃O⁺]

Since pH = -log[H₃O⁺],
pH = -log(1.483×10⁻⁶)
<em>pH = 5.83</em>


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