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drek231 [11]
3 years ago
13

At a certain temperature, the solubility of strontium arsenate, sr3(aso4)2, is 0.0560 g/l. what is the ksp of this salt at this

temperature?
Chemistry
1 answer:
REY [17]3 years ago
5 0
The solution for this problem is:
Get into moles first. .0560 grams over 540.8 grams per mole = 1.04 x l0^-4 moles 
Sr3(As04)2 = 3 Sr++(aq) plus 2 As04^-3(aq) 
Ksp = (Sr++)^3(As04^-3)^2 
(Sr++) = 3 X 1.04 x l0^-4= 3.11 x l0^-4 
(As04^-3) = 2 x 1.04 x l0^-4= 2.07 x l0^-4 
Ksp = (1.04 x l0^-4)^3 (2.07 x l0^-4)^2 which equals 4.82 x 10^-20
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3 years ago
A reactant decomposes with a half-life of 29.5 s when its initial concentration is 0.229 M. When the initial concentration is 0.
Dmitrij [34]

Answer :

The order of reaction is, 0 (zero order reaction).

The value of rate constant is, 0.00388Ms^{-1}

Explanation :

Half life : It is defined as the time in which the concentration of a reactant is reduced to half of its original value.

The general expression of half-life for nth order is:

t_{1/2}\propto \frac{1}{[A_o]^{n-1}}

or,

\frac{t_{1/2}_1}{t_{1/2}_2}=\frac{[A_2]^{n-1}}{[A_1]^{n-1}}

or,

n=\left(\frac{\log\frac{(t_{1/2})_1}{(t_{1/2})_2}}{\log\frac{(A)_2}{(A)_1}}\right )+1           .............(1)

where,

t_{1/2} = half-life of the reaction

n = order of reaction

[A] = concentration

As we are given:

Initial concentration of A = 0.229 M

Final concentration of A = 0.639 M

Initial half-life of the reaction = 29.5 s

Final half-life of the reaction = 82.3 s

Now put all the given values in the above formula 1, we get:

n=\left (\frac{\log \frac{29.5}{82.3}}{\log\frac{0.639}{0.229}}\right )+1

n=0.000196\approx 0

Thus, the order of reaction is, 0 (zero order reaction).

Now we have to determine the rate constant.

To calculate the rate constant for zero order the expression will be:

t_{1/2}=\frac{[A_o]}{2k}

When,

t_{1/2} = 29.5 s

[A_o] = 0.229 M

29.5s=\frac{0.229M}{2k}

k=0.00388Ms^{-1}

Thus, the value of rate constant is, 0.00388Ms^{-1}

4 0
3 years ago
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