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notka56 [123]
3 years ago
13

A possible mechanism for the overall reaction br2 (g) + 2no (g) → 2nobr (g) is no (g) + br2 (g) nobr2 (g) (fast) nobr2 (g) + no

(g) k2→ 2nobr (slow) the rate law for formation of nobr based on this mechanism is rate = ________. a possible mechanism for the overall reaction br2 (g) + 2no (g) 2nobr (g) is no (g) + br2 (g) nobr2 (g) (fast) nobr2 (g) + no (g) 2nobr (slow) the rate law for formation of nobr based on this mechanism is rate = ________. k1[br2]1/2 (k2k1/k-1)[no][br2]2 (k1/k-1)2[no]2 k1[no]1/2 (k2k1/k-1)[no]2[br2]
Chemistry
1 answer:
givi [52]3 years ago
7 0
The overall reaction is:
Br₂(g) + 2 NO(g) ↔ 2 NOBr(g)
rate law = k [Br₂][NO]²

The first step of the overall reaction is:
NO(g) + Br₂(g)   K₁⇄⇄K-1  NOBr₂(g)
rate law 1 = k₁ [Br₂][NO] or 
rate law 2 = k-1 [NOBr₂]

The second step of the overall reaction is:
NOBr₂(g) + NO(g)  →K₂→ 2 NOBr
rate law 3 = k₂[NOBr₂][NO]

So, rate law of overall reaction can be obtained as follows:
(rate law 1)*(rate law 3) / (rate law 2)
= [(k₁[Br₂][NO])* (K₂[NOBr₂][NO])] / k₋₁[NOBr₂]
= [k₁k₂/k₋₁][NO]²[Br₂]
So the correct answer is:
[k₁k₂/k₋₁][NO]² [Br₂]
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Assuming the reaction is first order in sucrose, determine the mass of sucrose that is hydrolyzed when 2.75 L of a 0.130 M sucro
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Answer:125.84g

Explanation:Sucrose is dissacharides an organic compound in the class of carbonhydrate with the chemical formula C11H22O11.molar concentration is given by number of moles/Volume,this implies that moles=molar concentration ×Volume=0.130M×2.75L=0.3575moles.

Furthermore,number of moles=Mass of Sucrose/molecular Mass of Sucrose.

From it's formular C11H22O11, molecular Mass is the addition of the mass number which is 12 for C,2 for H and 16 for oxygen,O.so molecular Mass of Sucrose is (12×11)+(2×22)+(16×11)=352.

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