<span>it tells you the sequence in which events occurred, not how long ago they occurred.</span>
Answer:
The options <u>(A) -</u>The rate law for a given reaction can be determined from a knowledge of the rate-determining step in that reaction's mechanism. and <u>(C) </u>-The rate laws of bimolecular elementary reactions are second order overall ,<u>is true.</u>
Explanation:
(A) -The rate law can only be calculated from the reaction's slowest or rate-determining phase, according to the first sentence.
(B) -The second statement is not entirely right, since we cannot evaluate an accurate rate law by simply looking at the net equation. It must be decided by experimentation.
(C) -Since there are two reactants, the third statement is correct: most bimolecular reactions are second order overall.
(D)-The fourth argument is incorrect. We must track the rates of and elementary phase that is following the reaction in order to determine the rate.
<u>Therefore , the first and third statement is true.</u>
The two first ones because it’s always the opposite
Answer:
The amount of work done on the system is 18234 J and the final positive sign means that this work corresponds to an increase in internal energy of the gas.
Explanation:
Thermodynamic work is called the transfer of energy between the system and the environment by methods that do not depend on the difference in temperatures between the two. When a system is compressed or expanded, a thermodynamic work is produced which is called pressure-volume work (p - v).
The pressure-volume work done by a system that compresses or expands at constant pressure is given by the expression:
W system= -p*∆V
Where:
- W system: Work exchanged by the system with the environment. Its unit of measure in the International System is the joule (J)
- p: Pressure. Its unit of measurement in the International System is the pascal (Pa)
- ∆V: Volume variation (∆V = Vf - Vi). Its unit of measurement in the International System is cubic meter (m³)
In this case:
- p= 10 atm= 1.013*10⁶ Pa (being 1 atm= 101325 Pa)
- ΔV= 2 L- 20 L= -18 L= -0.018 m³ (being 1 L=0.001 m³)
Replacing:
W system= -1.013*10⁶ Pa* (-0.018 m³)
Solving:
W system= 18234 J
<u><em>The amount of work done on the system is 18234 J and the final positive sign means that this work corresponds to an increase in internal energy of the gas.</em></u>
Answer : The correct option is, 13.7 mole
Solution : Given,
Moles of 
= 27.4 moles
The given balanced chemical reaction is,
From the balanced chemical reaction, we conclude that
As, 2 moles of react with 1 moles of 
So, 27.4 moles of react with 
moles of
Therefore, the number of moles of oxygen required are, 13.7 moles
