A chemist measures the solubility of lead(ii) bromide in water to be 2. 96 g/l. calculate the ksp value for the solid. the ksp v
1 answer:
The solubility product, ksp of PbBr₂ is 2.102 × 10⁻⁶
<h3>What is solubility?</h3>The solubility of a solute is defined as the maximum amount of that solute that can be dissolved in a known quantity of solvent at a given temperature.
<h3>What is a solubility product? </h3>Some salts are sparingly soluble in a solvent. For them, we calculate the solubility product.
It is an equilibrium constant that defines the relationship between a solid and its respective ions in an aqueous solution in equilibrium.
The greater the solubility product, the greater the solubility and vice versa.
Here, the solubility of PbBr₂ = 2.96 g/l
Molar solubility of PbBr₂ = = 2.96/367 = 8.07 × 10⁻³
At equilibrium,
1 mole of PbBr2 dissociates into 1 mole of Pb²⁺ ions and 2 moles of Br⁻
Let the molar concentration of Pb²⁺ be x, then the molar concentration of Br⁻ is 2x
Ksp = x.(2x)²
= 4x³
Substitute, x = 8.07 × 10⁻³
Ksp = 4 (8.07 × 10⁻³)³
= 2.102 × 10⁻⁶
Thus, The ksp of PbBr₂ is 2.102 × 10⁻⁶
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Answer:
All of the above.
Explanation:
In positive deviation from Raoult's Law occur when the vapour pressure of components is greater than what is expected value in Raoult's law.
When a solution is non ideal then it shows positive or negative deviation.
Let two solutions A and B to form non- ideal solutions.let the vapour pressure of component A is and vapour pressure of component B is
.
= Vapour pressure of component A in pure form
= Vapour pressure of component B in pure form
=Mole fraction of component A
=Mole fraction of component B
The interaction between A- B is less than the interaction A- A and B-B interaction.Therefore, the escaping tendency of liquid molecules in mixture is greater than the escaping tendency in pure form.Hence, the vapour pressure of a mixture is greater than the initial value of vapour pressure.
,
Therefore,
Therefore, the enthalpy of mixing is greater than zero and change in volume is greater than zero.
Hence, option a,b,c and d are true.
Answer:
V = 38.48 L
Explanation:
Given that,
No. of moles = 1.5 mol
Pressure, P = 700 torr
Temperature, T = 15°C = 288 K
We need to find the volume of the gas. The ideal gas equation is given by :
, R = L.Torr.K⁻¹.mol⁻¹
So, the required volume is equal to 38.48 L.