Answer:
The value of 
is 0.02495.
Explanation:
Initial concentration of 
gas = 0.675 M
Initial concentration of 
gas = 0.973 M
Equilibrium concentration of mustard gas = 0.35 M
initially
0.675 M 0.973 M 0
At equilibrium ;
(0.675-0.35) M (0.973-2 × 0.35) M 0.35 M
The equilibrium constant is given as :
![K_c=\frac{[S(CH_2CH_2Cl)_2]}{[SCl_2][C_2H_4]^2}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BS%28CH_2CH_2Cl%29_2%5D%7D%7B%5BSCl_2%5D%5BC_2H_4%5D%5E2%7D)
The relation between and 
are :
where,
= equilibrium constant at constant pressure = ?
= equilibrium concentration constant =14.45
R = gas constant = 0.0821 L⋅atm/(K⋅mol)
T = temperature = 20.0°C =20.0 +273.15 K=293.15 K
= change in the number of moles of gas = [(1) - (1 + 2)]=-2
Now put all the given values in the above relation, we get:
The value of is 0.02495.
The lattice energy of the compounds is distributed in the following decreasing order of magnitude: MgO > CaO > NaF > KCl.
<h3>KCl or NaF, which has a higher lattice energy?</h3>
The lattice energy increases with increasing charge and decreasing ion size.(Refer to Coulomb's Law.)MgF2 > MgO.Following that, we can examine NaF and KCl (both of which have 1+ and 1-charges), as well as atomic radii.NaF will have a larger LE than KCl since Na is smaller then K and F was smaller than Cl.
<h3>MgO or CaO, which has a larger lattice energy?</h3>
MGO is more difficult than CaO, hence.This is because "Mg" (two-plus) ions are smaller than "Ca" (two-plus) ions in size.MgO has higher lattice energy as a result.
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Answer:
- 10.555 kJ/mol.
Explanation:
∵ ∆G°rxn = ∆H°rxn - T∆S°rxn.
Where, ∆G°rxn is the standard free energy change of the reaction (J/mol).
∆H°rxn is the standard enthalpy change of the reaction (J/mol).
T is the temperature of the reaction (K).
∆S°rxn is the standard entorpy change of the reaction (J/mol.K).
∵ ∆H°rxn = ∑∆H°products - ∑∆H°reactants
<em>∴ ∆H°rxn = (2 x ∆H°f NOCl) - (1 x ∆H°f Cl₂) - (2 x ∆H°f NO) </em>= (2 x 51.71 kJ/mol) - (1 x 0) - (2 x 90.29 kJ/mol) = - 77.16 kJ/mol.
∵ ∆S°rxn = ∑∆S°products - ∑∆S°reactants
<em>∴ ∆S°rxn = (2 x ∆S° NOCl) - (1 x ∆S° Cl₂) - (2 x ∆S° NO) </em>= (2 x 261.6 J/mol.K) - (1 x 223.0 J/mol.K) - (2 x 210.65 J/mol.K) =<em> - 121.1 J/mol.K. = - 0.1211 kJ/mol.K.</em>
<em></em>
∵ ∆G°rxn = ∆H°rxn - T∆S°rxn.
<em>∴ ∆G°rxn = ∆H°rxn - T∆S°rxn </em>= (- 77.16 kJ/mol) - (550 K)(- 0.1211 kJ/mol.K) = <em>- 10.555 kJ/mol.</em>
Answer:
Hypothesis
Explanation:
The following steps are applicable when we wish to prove a specific fact:
- a hypothesis is made; this is a statement that we provide after some observations and we wish to either prove or deny it;
- multiple experiments are carried out in order to gather significantly substantial amount of data that can be then further analyzed and any tendencies can be noticed;
- based on the data gathered, conclusions are made: we either prove or deny the hypothesis. If hypothesis is proved, it may become a theory over long time.
In the context of this problem, we're at the first step where we make a hypothesis.
And the significant amount of volume can be differed by its solitude
