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3 years ago

Basic points in Lewis and Langmuir theory of electrovalency

1 answer:

6 0

The correct answer for the question that is being presented above is this one: "Electrovalency is characterized with the transferring of one or more electrons from one atom to another together with the formation of ions and as well as the number of positive and negative charges.

The Lewis and Langmuir theory of electrovalency (and as well as Kossel's) is dealing with Ionic bonds.

Lewis: electron-pair sharing, octet rule, Lewis Symbols or StructureLangmuir: introduced term "covalent" bond, and popularized Lewis's ideas

The Lewis-Langmuir electron-pair or covalent bond is referred as the homopolar bond, where the complete transfer of electrons give rise to ionic, or electrovalent bond (1) through attraction of opposite charges.

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A solution was prepared by dissolving 0.800 g of sulfur S8, in 100.0 g of acetic acid, HC2H3O2. Calculate the freezing point and

Romashka [77]

Answer: The freezing point of solution is 16.5°C and the boiling point of solution is 118.2°C

Explanation:

To calculate the molality of solution, we use the equation:

$Molality=\frac{m_{solute}\times 1000}{M_{solute}\times W_{solvent}\text{ in grams}}$

Where,

$m_{solute}$ = Given mass of solute $(S_8)$ = 0.800 g

$M_{solute}$ = Molar mass of solute $(S-8)$ = 256.52 g/mol

$W_{solvent}$ = Mass of solvent (acetic acid) = 100.0 g

Putting values in above equation, we get:

$\text{Molality of solution}=\frac{0.800\times 1000}{256.52\times 100.0}\\\\\text{Molality of solution}=0.0312m$

Calculation for freezing point of solution:

Depression in freezing point is defined as the difference in the freezing point of water and freezing point of solution.

$\Delta T_f=\text{freezing point of acetic acid}-\text{Freezing point of solution}$

To calculate the depression in freezing point, we use the equation:

$\Delta T_f=iK_fm$

or,

$\text{Freezing point of acetic acid}-\text{Freezing point of solution}=iK_fm$

where,

Freezing point of acetic acid = 16.6°C

i = Vant hoff factor = 1 (for non-electrolyte)

$K_f$ = molal freezing point depression constant = 3.59°C/m

m = molality of solution = 0.0312 m

Putting values in above equation, we get:

$16.6^oC-\text{freezing point of solution}=1\times 3.59^oC/m\times 0.0312m\\\\\text{Freezing point of solution}=16.5^oC$

Hence, the freezing point of solution is 16.5°C

Calculation for boiling point of solution:

Elevation in boiling point is defined as the difference in the boiling point of solution and freezing point of pure solution.

The equation used to calculate elevation in boiling point follows:

$\Delta T_b=\text{Boiling point of solution}-\text{Boiling point of acetic acid}$

To calculate the elevation in boiling point, we use the equation:

$\Delta T_b=iK_bm$

or,

$\text{Boiling point of solution}-\text{Boiling point of acetic acid}=iK_fm$

where,

Boiling point of acetic acid = 118.1°C

i = Vant hoff factor = 1 (for non-electrolyte)

$K_f$ = molal boiling point elevation constant = 3.08°C/m

m = molality of solution = 0.0312 m

Putting values in above equation, we get:

$\text{Boiling point of solution}-118.1^oC=1\times 3.08^oC/m\times 0.0312m\\\\\text{Boiling point of solution}=118.2^oC$

Hence, the boiling point of solution is 118.2°C

8 0

3 years ago

A 8.00 L tank at 26.9 C is filled with 5.53 g of dinitrogen difluoride gas and 17.3 g of sulfur hexafluoride gas. You can assume

pshichka [43]

Answer:

mole fraction of N_2 O = 0.330

mole of fraction SF_4 = 0.669

PRESSURE OF N_2 O = 39127.053 Pa

pressure of SF_4 = 792126.36

Total pressure = 118253.413 Pa

Explanation:

Given data:

volume of tank 8 L

Weight of dinitrogen difluoride gas 5.53 g

weight of sulphur hexafluoride gas 17.3 g

Amount of $N_2 O = \frac{5.53}{14*2 + 16} = 0.1256 mol$

amount of $SF_4 = \frac{17.3}{32.1 + 19*4} = 0.254 mol$

mole fraction of $N_2 O = \frac{0.1256}{0.1256 + 0.254} = 0.330$

mole of fraction $SF_4 = \frac{0.254}{0.1256 + 0.254} = 0.669$

PV = nRT

P of N_2 O $= \frac{0.1256 *8.31 (273 + 26.9}{0.008} = 39127.053 Pa$

mole of SF_4 $=\frac{0.254 *8.31*(273+26.9)}{.008} = 79126.36 Pa$

Total pressure = 39127.053 + 79126.36 = 118253.413 Pa

6 0

3 years ago

Help please !!!!!!!!!!

Vedmedyk [2.9K]

25 sugar because the mass should be equal on both sides

5 0

3 years ago

What happens when an acid reacts with a base?

shepuryov [24]

Answer:

They neutralize each other

3 0

2 years ago

Read 2 more answers

. If this same atom with 22 protons and 19 electrons were to gain 3 electrons, the net charge on the atom would be

mina [271]

Answer:

neutral

Explanation:

19+3=22

22 protons & 22 neutrons --> neutral net charge

3 0

2 years ago