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Sidana [21]
3 years ago
9

Scoring Scheme: 3-3-2-1 When you use the half reaction method to balance the redox reaction between one mole of NBS and ascorbic

acid to give L-dehydroascorbic acid and succinimide, how many moles of electrons are transferred?

Chemistry
1 answer:
erica [24]3 years ago
6 0
<span>In the redox reaction between one mole of NBS and ascorbic acid, ascorbic acid undergoes oxidation reaction to form </span><span>L-dehydroascorbic acid.

On other hand, N-bromo</span>succinimide (NBS) undergoes reduction to form <span>succinimide.

Electron transferred during this process is two. Complete reaction is attached below for quick reference.

Thus, one molecule of NBS reacts with one molecule of </span>ascorbic acid, during this redox reaction. For each molecule reacting, two electrons are transferred. 

Thus, when one mole of NBS reacts with one mole of ascorbic acid, 2 x Na moles of electrons will be transferred. It may be noted here that, Na = Avagadro's number = 6.022 X 10^23.

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In a particular experiment, 2.50-g samples of each reagent are reacted. The theoretical yield of lithium nitride is ________ g.
Neporo4naja [7]

Answer:

4.18 g

Explanation:

The formula for the calculation of moles is shown below:

moles = \frac{Mass\ taken}{Molar\ mass}

Given: For Li

Given mass = 2.50 g

Molar mass of Li  = 6.94 g/mol

<u>Moles of Li  = 2.50 g / 6.94 g/mol = 0.3602 moles</u>

Given: For N_2

Given mass = 2.50 g

Molar mass of N_2 = 28.02 g/mol

<u>Moles of N_2 = 2.50 g / 28.02 g/mol = 0.08924 moles</u>

According to the given reaction:

6Li+N_2\rightarrow 2Li_3N

6 moles of Li react with 1 mole of N_2

1 mole of Li react with 1/6 mole of N_2

0.3602 mole of Li react with \frac {1}{6}\times 0.3602 mole of N_2

Moles of N_2 that will react = 0.06 moles

Available moles of N_2 = 0.08924 moles

N_2 is in large excess. (0.08924 > 0.06)

Limiting reagent is the one which is present in small amount. Thus,

Li is limiting reagent.

The formation of the product is governed by the limiting reagent. So,

6 moles of Li gives 2 mole of Li_3N

1 mole of Li gives 2/6 mole of Li_3N

0.3602 mole of Li react with \frac {2}{6}\times 0.3602 mole of Li_3N

Moles of Li_3N = 0.12

Molar mass of Li_3N = 34.83 g/mol

Mass of Li_3N = Moles × Molar mass = 0.12 × 34.83 g = 4.18 g

<u>Theoretical yield = 4.18 g</u>

5 0
3 years ago
An ideal gas in a 1.25-gallon container is at a temperature of 125 degrees Celsius and pressure of 2.5 atmospheres. If the gas i
Tresset [83]
You will need the equation PV = nRT

P = Pressure in kPa
V = Volume in L
n = moles
R = 8.314 (constant)
T = Temperature in Kelvin 

First convert 2.5 atm into kPa:

2.5 X 101.3 = 253.25 kPa

Convert 125 Celsius into Kelvin:

125 + 273 = 398 K

Convert Gallons to Litres:

1.25  X 3.79 = 4.74 L

Plug your values into the equation to solve for n:

(253.25)(4.74) = n(8.314)(398)

n = (253.25)(4.74)/(8.314)(398)

n = 0.362 moles

Now use M = m/n to solve for the mass of O2

M = Molar Mass 
M = mass
n= moles

32 = m/(0.362)

m = (32)(0.362) 

m = 11.58g
8 0
3 years ago
HELP ME PLS I NEED HELP I HAVE 5MINS
Leviafan [203]

Answer:

K

Explanation:

Since the blood moves from the body to the right atrium to the right ventricle

3 0
2 years ago
When did homo spiens leave africa
german

homo sapiens leave africa at approximately 200,000 years ago.

7 0
3 years ago
Imagine that you are given the mass spectra of these two compounds, but the spectra are missing the compound names.
12345 [234]

The structures of the isomers and the m/z values of their peaks are not given in the question. The complete question is provided in the attachment

Answer:

Compound 2 (2,5-dimethylhexane) will not have the peaks at 29 and 85 m/z

Explanation:

The fragmentation of molecules by electron ionization of mass spectrometer occurs according to Stevenson's Rule, which states that "The most probable fragmentation is the one that leaves the positive charge on the fragment with the lowest ionization energy". This is much like the Markovnikov's Rule in organic chemistry which has predicted the formation of most stable carbocation and the addition of hydrogen halide to it.

The mass spectra of compound 1 (2,4-dimethylhexane) will contain all the m/z values mentioned in the question. Each peak indicate towards homologous series of fragmentation product of the compound 1. The first peak can be attributed to ethyl carbocation (m/z = 29), with the increase of 14 units the next peak indicates towards propyl carbocation (m/z = 43) and onwards until molecular ion peak of 114 m/z.

Compound 2 (2,5-dimethylhexane) structure shows that the cleavage  of C-C bond will not yield a stable ethyl and hexyl carbocation. Hence, no peaks will be observed at 29 and 85 m/z. The absence of these two peaks can be used to distinguish one isomer from the other.

5 0
3 years ago
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