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3 years ago

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Chemistry

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sdas [7]3 years ago

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At 298 K, the osmotic pressure of a glucose solution (C6H12O6 (aq)) is 12.1 atm. Calculate the freezing point of the solution. T

Anarel [89]

Answer: The freezing point of solution is -0.974°C

Explanation:

To calculate the concentration of solute, we use the equation for osmotic pressure, which is:

$\pi=iMRT$

where,

$\pi$ = osmotic pressure of the solution = 12.1 atm

i = Van't hoff factor = 1 (for non-electrolytes)

M = molarity of solute = ?

R = Gas constant = $0.0821\text{ L atm }mol^{-1}K^{-1}$

T = temperature of the solution = 298 K

Putting values in above equation, we get:

$12.1atm=1\times M\times 0.0821\text{ L.atm }mol^{-1}K^{-1}\times 298K\\\\M=\frac{12.1}{1\times 0.0821\times 298}=0.495M$

This means that 0.495 moles of glucose is present in 1 L or 1000 mL of solution

To calculate the mass of solution, we use the equation:

$\text{Density of substance}=\frac{\text{Mass of substance}}{\text{Volume of substance}}$

Density of solution = 1.034 g/mL

Volume of solution = 1000 mL

Putting values in above equation, we get:

$1.034g/mL=\frac{\text{Mass of solution}}{1000mL}\\\\\text{Mass of solution}=(1.034g/mL\times 1000mL)=1034g$

To calculate the number of moles, we use the equation:

$\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}$

Moles of glucose = 0.495 moles

Molar mass of glucose = 180.16 g/mol

Putting values in above equation, we get:

$0.495mol=\frac{\text{Mass of glucose}}{180.16g/mol}\\\\\text{Mass of glucose}=(0.495mol\times 180.16g/mol)=89.18g$

Depression in freezing point is defined as the difference in the freezing point of pure solution and freezing point of solution.

The equation used to calculate depression in freezing point follows:

$\Delta T_f=\text{Freezing point of pure solution}-\text{Freezing point of solution}$

To calculate the depression in freezing point, we use the equation:

$\Delta T_f=iK_fm$

Or,

$\text{Freezing point of pure solution}-\text{Freezing point of solution}=i\times K_f\times \frac{m_{solute}\times 1000}{M_{solute}\times W_{solvent}\text{ (in grams)}}$

where,

Freezing point of pure solution = 0°C

i = Vant hoff factor = 1 (For non-electrolytes)

$K_f$ = molal freezing point elevation constant = 1.86°C/m

$m_{solute}$ = Given mass of solute (glucose) = 89.18 g

$M_{solute}$ = Molar mass of solute (glucose) = 180.16 g/mol

$W_{solvent}$ = Mass of solvent (water) = [1034 - 89.18] g = 944.82 g

Putting values in above equation, we get:

$0-\text{Freezing point of solution}=1\times 1.86^oC/m\times \frac{89.18\times 1000}{180.16g/mol\times 944.82}\\\\\text{Freezing point of solution}=-0.974^oC$

Hence, the freezing point of solution is -0.974°C

8 0

3 years ago

Zinc sulfate is a 2-ion electrolyte,

Gekata [30.6K]

Answer: The value of i is 1.4 and 40% dissociation of 100 particles of zinc sulfate will yield 60 undissociated particles.

Explanation:

The equation used to calculate the Vant' Hoff factor in dissociation follows:

$\alpha =\frac{i-1}{n-1}$

where,

$\alpha$ = degree of dissociation = 40% = 0.40

i = Vant' Hoff factor

n = number of ions dissociated = 2

Putting values in above equation, we get:

$0.40=\frac{i-1}{2-1}\\\\0.40=i-1\\\\i=1.4$

The equation used to calculate the degee of dissociation follows:

$\alpha =\frac{\text{Number of particles dissociated}}{\text{Total number of particles taken}}$

Total number of particles taken = 100

Degree of dissociation = 40% = 0.40

Putting values in above equation, we get:

$0.40=\frac{\text{Number of particles dissociated}}{100}\\\\\text{Number of particles dissociated}=(0.40\times 100)=40$

This means that 40 particles are dissociated and 60 particles remain undissociated in the solution.

Hence, 40% dissociation of 100 particles of zinc sulfate will yield 60 undissociated particles.

7 0

2 years ago

What happens to the atomic mass of an element moving from left to right within a period

JulsSmile [24]

Answer:

As you move across a period, the atomic mass increases because the atomic number also increases. ... The atomic mass for any given atom mainly comes from the mass of the protons and neutrons.

Explanation:

4 0

3 years ago

What is the chemical formula for the compound formed between chromium(iii) and the sulfate ion

Anastasy [175]

Cr2(SO4)3 is the formula

7 0

3 years ago

Read 2 more answers

Look at the periodic table in Appendix 1. Name two elements that do not appear in order of their relative atomic masses.

e-lub [12.9K]

iodine which should appear before tellurium and argon which should appear after potassium