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arlik [135]
4 years ago
6

A 75.0 mL volume of 0.200 M NH3 (Kb=1.8*10^-5) is titrated with 0.500 M HNO3. Calculate the pH after the addition of 25.0 mL of

HNO3.
Chemistry
1 answer:
Murljashka [212]4 years ago
3 0
 <span>pKb = - log 1.8 x 10^-5 = 4.7 
moles NH3 = 0.0750 L x 0.200 M=0.0150 
moles HNO3 = 0.0270 L x 0.500 M= 0.0135 
the net reaction is 
NH3 + H+ = NH4+ 
moles NH3 in excess = 0.0150 - 0.0135 =0.0015 
moles NH4+ formed = 0.0135 
total volume = 75.0 + 27.0 = 102.0 mL = 0.102 L 
[NH3]= 0.0015/ 0.102 L=0.0147 M 
[NH4+] = 0.0135/ 0.102 L = 0.132 M 

pOH = pKb + log [NH4+]/ [NH3]= 4.7 + log 0.132/ 0.0147=5.65 
pH = 14 - pOH = 14 - 5.65 =8.35 

I hope my answer has come to your help. Thank you for posting your question here in Brainly.
</span>
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Calcium dihydrogen phosphate, Ca(H₂PO₄)₂, and sodium hydrogen carbonate, NaHCO₃, are ingredients of baking powder that react to
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0.012 mol of CO₂ can be produced from 3.50 g of baking powder.

<h3>What is baking powder?</h3>
  • Baking powder is a dry chemical leavener composed of carbonate or bicarbonate and a weak acid.
  • The addition of a buffer, such as cornstarch, prevents the base and acid from reacting prematurely.
  • Baking powder is used in baked goods to increase volume and lighten the texture.

To find how many moles of CO₂ are produced from 1.00 g of baking powder:

The balanced equation is:

  • Ca(H₂PO₄)₂(s) + 2NaHCO₃(s) → 2CO₂(g) + 2H₂O(g) + CaHPO₄(s) + Na₂HPO₄(s)

On 3.50 g of baking power:

  • mCa(H₂PO₄)₂ = 0.35 × 3.50 = 1.225 g
  • mNaHCO₃ = 0.31 × 3.50 = 1.085 g

The molar masses are: Ca = 40 g/mol; H = 1 g/mol; P = 31 g/mol; O = 16 g/mol; Na = 23 g/mol; C = 12 g/mol.

So,

  • Ca(H₂PO₄)₂: 40 + 4 × 1 + 31 + 8 × 16 = 203 g/mol
  • NaHCO₃: 23 + 1 + 12 + 3 × 16 = 84 g/mol

The number of moles is the mass divided by molar mass, so:

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  • nNaHCO₃ = 1.085/84 = 0.0129 mol

First, let's find which reactant is limiting.

Testing for Ca(H₂PO₄)₂, the stoichiometry is:

  • 1 mol of Ca(H₂PO₄)₂ ---------- 2 mol of NaHCO₃
  • 0.006 of Ca(H₂PO₄)₂ -------- x

By a simple direct three rule:

  • x = 0.012 mol

So, NaHCO₃ is in excess.

The stoichiometry calculus must be done with the limiting reactant, then:

  • 1 mol of Ca(H₂PO₄)₂ ------------- 2 mol of CO₂
  • 0.006 of Ca(H₂PO₄)₂ -------- x

By a simple direct three rule:

  • x = 0.012 mol of CO₂

Therefore, 0.012 mol of CO₂ can be produced from 3.50 g of baking powder.

Know more about baking powder here:

brainly.com/question/20628766

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The correct question is given below:

Calcium dihydrogen phosphate, Ca(H2PO4)2, and sodium hydrogen carbonate, NaHCO3, are ingredients of baking powder that react with each other to produce CO2, which causes dough or batter to rise: Ca(H2PO4)2(s) + NaHCO3(s) → CO2(g) + H2O(g) + CaHPO4(s) + Na2HPO4(s)[unbalanced] If the baking powder contains 31.0% NaHCO3 and 35.0% Ca(H2PO4)2 by mass: (a) How many moles of CO2 are produced from 3.50 g of baking powder?

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Diffusion should be remembered as the movement of molecules of matters from a highly concentrated region otherwise called hypertonic region to a less concentrated region called hypotonic region through a permeable medium until there is an equilibrium in the system. Since diffusion is expected to involve the movement of molecules, and any matter that can exhibit diffusion is said to have moving molecules, therefore, the kinetic molecular theory of matter is proven to be accurate with the observed movement of iodine molecules in the test tube. This shows that even the molecules of solid matters are in constant random motion, this is made more convincing when these molecules migrate without the addition of external energy source like heat, which then help to understand that the natural iodine molecules are in constant random motion, as they are changed to gaseous state without passing through liquid state, a phenomenon called sublimation.

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