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Rudik [331]
3 years ago
8

g A chemist combines 59.9 mL of 0.282 M potassium bromide with 15.4 mL of 0.512 M silver nitrate. (a) How many grams of silver b

romide will precipitate
Chemistry
1 answer:
Rufina [12.5K]3 years ago
6 0

Answer:

m_{AgBr}=1.48gAgBr

Explanation:

Hello,

In this case, the undergoing chemical reaction is:

KBr(aq)+AgNO_3(aq)\rightarrow AgBr(s)+KNO_3(aq)

Thus, since the potassium bromide and silver nitrate are in a 1:1 mole ratio, the first step is to identify the limiting reactant, by considering the reacting volumes of reactants in order to compute the available moles of potassium bromide and the moles of potassium bromide consumed by the 15.4 mL of 0.512-M solution of silver nitrate:

n_{KBr}=0.0599L*0.282\frac{molKBr}{L} =0.0169molKBr\\\\n_{KBr}^{consumed}=0.0154L*0.512\frac{molAgNO_3}{L} *\frac{1molKBr}{1molAgNO_3}=0.00788molKBr

In such a way, since less moles are consumed than available, we infer that silver nitrate is the limiting reactant, for which the resulting grams of silver bromide (molar mass 187.8 g/mol) result:

m_{AgBr}=0.00788molAgNO_3*\frac{1molAgBr}{1molAgNO_3} *\frac{187.8gAgBr}{1molAgBr} \\\\m_{AgBr}=1.48gAgBr

Best regards.

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Predict which of the following pairs of solutions, when mixed together, will cause a precipitate to form. (Select all that apply
Kay [80]

Answer:

25 mL of 1 × 10–5 M Co(NO₃)₂ and 75 mL of 5 × 10–4 M Na₂S

500 mL of 7.5 × 10–4 M AlCl₃ and 100 mL of 1.7 × 10–5 M Hg₂(NO₃)₂.

650 mL of 0.0080 M K₂SO₄ and 175 mL of 0.15 M AgNO₃

Explanation:

When 2 compounds that produce an insoluble substance are mixed together, <em>A precipitate will be formed if Q of reaction > Ksp</em>

For the solutions:

1.5 L of 0.025 M BaCl₂ and 1.25L of 0.014 M Pb(NO₃)₂.

Ksp is:

PbCl₂(s) ⇄ Pb²⁺(aq) + 2Cl⁻(aq)

Ksp = 2.4x10⁻⁴ = [Pb²⁺][Cl⁻]²

Molar concentration of each ion is:

[Pb²⁺] =  1.25L ₓ (0.014mol / L) = 0.0175mol / 2.75L = 6.36x10⁻³M

[Cl⁻] = 2 ₓ 1.5L ₓ (0.025mol / L) = 0.075mol / 2.75L = 0.0273M

Replacing in Ksp expression to find Q:

Q = [6.36x10⁻³M][0.0273M]² = 4.73x10⁻⁶

As Q < Ksp, the mixture will not produce a precipitate.

25 mL of 1 × 10–5 M Co(NO₃)₂ and 75 mL of 5 × 10–4 M Na₂S

Ksp is:

CoS(s) ⇄ Co²⁺(aq) + S²⁻(aq)

Ksp = 4.0x10⁻²¹ = [Co²⁺][S²⁻]

Molar concentration of each ion is:

[Co²⁺] =  0.025L ₓ (1x10⁻⁵mol / L) = 2.5x10⁻⁷mol / 0.1L = 2.5x10⁻⁶M

[S²⁻] = 0.075L ₓ (5x10⁻⁴mol / L) = 3.75x10⁻⁵mol / 0.1L = 3.75x10⁻⁴M

Replacing in Ksp expression to find Q:

Q = [2.5x10⁻⁶M][3.75x10⁻⁴M] = 9.38x10⁻⁶

As Q > Ksp, the mixture will produce a precipitate.

500 mL of 7.5 × 10–4 M AlCl₃ and 100 mL of 1.7 × 10–5 M Hg₂(NO₃)₂.

Ksp is:

Hg₂Cl₂(s) ⇄ 2Hg⁺(aq) + 2Cl⁻(aq)

Ksp = 3.5x10⁻¹⁸ = [Hg⁺]²[Cl⁻]²

Molar concentration of each ion is:

[Hg⁺] =  2ₓ0.100L ₓ (1.7x10⁻⁵mol / L) = 3.4x10⁻⁶mol / 0.6L = 5.67x10⁻⁶M

[Cl⁻] = 3 ₓ 0.500L ₓ (7.5x10⁻⁴mol / L) = 1.125x10⁻³mol / 0.6L = 1.88x10⁻³M

Replacing in Ksp expression to find Q:

Q = [5.67x10⁻⁶M]²[1.88x10⁻³M]² = 1.14x10⁻⁶

As Q > Ksp, the reaction will produce a precipitate.

650 mL of 0.0080 M K₂SO₄ and 175 mL of 0.15 M AgNO₃

Ksp is:

Ag₂SO₄(s) ⇄ 2Ag⁺(aq) + SO₄²⁻(aq)

Ksp = 1.5x10⁻⁵ = [Ag⁺]²[SO₄²⁻]

Molar concentration of each ion is:

[Ag⁺] =  0.175L ₓ (0.15mol / L) = 0.02625mol / 0.825L = 0.0318M

[SO₄²⁻] = 0.650L ₓ (0.080mol / L) = 0.052mol / 0.825L = 0.0630M

Replacing in Ksp expression to find Q:

Q = [0.0318M]²[0.0630M] = 6.37x10⁻⁵

As Q > Ksp, the reaction will produce a precipitate.

6 0
3 years ago
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