Answer:
Activation energy of phenylalanine-proline peptide is 66 kJ/mol.
Explanation:
According to Arrhenius equation-
, where k is rate constant, A is pre-exponential factor,
is activation energy, R is gas constant and T is temperature in kelvin scale.
As A is identical for both peptide therefore-
![\frac{k_{ala-pro}}{k_{phe-pro}}=e^\frac{[E_{a}^{phe-pro}-E_{a}^{ala-pro}]}{RT}](https://tex.z-dn.net/?f=%5Cfrac%7Bk_%7Bala-pro%7D%7D%7Bk_%7Bphe-pro%7D%7D%3De%5E%5Cfrac%7B%5BE_%7Ba%7D%5E%7Bphe-pro%7D-E_%7Ba%7D%5E%7Bala-pro%7D%5D%7D%7BRT%7D)
Here
, T = 298 K , R = 8.314 J/(mol.K) and 
So, ![\frac{0.05}{0.005}=e^{\frac{[E_{a}^{phe-pro}-(60000J/mol)]}{8.314J.mol^{-1}.K^{-1}\times 298K}}](https://tex.z-dn.net/?f=%5Cfrac%7B0.05%7D%7B0.005%7D%3De%5E%7B%5Cfrac%7B%5BE_%7Ba%7D%5E%7Bphe-pro%7D-%2860000J%2Fmol%29%5D%7D%7B8.314J.mol%5E%7B-1%7D.K%5E%7B-1%7D%5Ctimes%20298K%7D%7D)
(rounded off to two significant digit)
So, activation energy of phenylalanine-proline peptide is 66 kJ/mol
Answer:
B.
Explanation:
Increased stability in fluoride ion.
Alpha particle has a mass of 4 (Two protons and two neutrons)
Neutron has a mass of 1
Beta particle has a mass of about 0 (Electron)
Proton has a mass of 1
So the answer is (2) Beta particle
Answer;
= C3H5
Explanation and solution;
1 mole of CO2 contains 44 g, of which 12 g are carbon
Thus, mass of carbon in 9.32 g will be;
(12/44) × 9.32 g = 2.542 g
Mass of Hydrogen in 3.18 g of water;
= (2/18) × 3.18 g = 0.353 g
we then find the number of moles;
Moles of carbon ; 2.542 /12 = 0.2118 moles
Moles of Hydrogen = 0.353 moles
The ratios of C ; H ;
= 1 : 0.353 /0.2118
= 1 : 5/3
= 3: 5
Therefore; the empirical formula of the hydrogen carbon is; C3H5
Reactivity is not a physical property because it's a characteristic of a chemical element or compound and is involved in chemical process.