The relative volumes of chloroform and water that should be used is 9:10
Concentration of solution in chloroform =
( moles of chloroform )
Concentration of solution in water =
( moles of water )
Dissociation constant at
; 
Concentration of solution in chloroform / Concentration of solution in water
Meaning;

Since
mole is present in chloroform and
mole is present in water, Total mole of Caffeine present is 
Now, we substitute our given values into the equation

Therefore, the relative volumes of chloroform and water that should be used is 9:10
Learn more; brainly.com/question/11060225
Answer : The time taken for the reaction is, 28 s.
Explanation :
Expression for rate law for first order kinetics is given by :
![k=\frac{2.303}{t}\log\frac{[A_o]}{[A]}](https://tex.z-dn.net/?f=k%3D%5Cfrac%7B2.303%7D%7Bt%7D%5Clog%5Cfrac%7B%5BA_o%5D%7D%7B%5BA%5D%7D)
where,
k = rate constant = 0.0632
t = time taken for the process = ?
= initial amount or concentration of the reactant = 1.28 M
= amount or concentration left time 't' = 
Now put all the given values in above equation, we get:


Therefore, the time taken for the reaction is, 28 s.
Just use the Heisenberg Uncertainty principle:
<span>ΔpΔx = h/2*pi </span>
<span>Δp = the uncertainty in momentum </span>
<span>Δx = the uncertainty in position </span>
<span>h = 6.626e-34 J s (plank's constant) </span>
<span>Hint: </span>
<span>to calculate Δp use the fact that the uncertainty in the momentum is 1% (0.01) so that </span>
<span>Δp = mv*(0.01) </span>
<span>m = mass of electron </span>
<span>v = velocity of electron </span>
<span>Solve for Δx </span>
<span>Δx = h/(2*pi*Δp) </span>
<span>And that is the uncertainty in position. </span>
Metal rusts when it oxidized around moisture.