<u>Answer:</u> To prepare the solution of given molarity, we add 63.8 g of copper (II) sulfate to the solution.
<u>Explanation:</u>
To calculate the number of moles for given molarity, we use the equation:

Molarity of copper(II)sulfate solution = 0.400 M
Volume of solution = 1.00 L
Putting values in above equation, we get:

To calculate the mass of copper(II)sulfate for given number of moles, we use the equation:

Molar mass of copper(II)sulfate = 159.61 g/mol
Moles of copper(II)sulfate = 0.400 moles
Putting values in above equation, we get:

Hence, to prepare the solution of given molarity, we add 63.8 g of copper (II) sulfate to the solution.