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gizmo_the_mogwai [7]
2 years ago
15

1. Rank the following compounds in order of decreasing acid strength using periodic trends. Rank the acids from strongest to wea

kest.
A. HCl
B. H2S
C. HBr
D. BH3
2. Without consulting the table of acid-dissociation constants, match the following acids to the given Ka1 values.
1. H2S
2. H2SO3
3. H2SO4
A. Kal = 1.7 x 10^-7
B. Kal = 1.7 x 10^-2
C. Kal = very large
Chemistry
1 answer:
Nookie1986 [14]2 years ago
7 0

Answer:

ESCALAS MAYORES (D, E, G, A, B) Porfavor necesito ayuda,te lo agradecería muchísimo!!

Es urgente

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Match the part of the wave to the diagram
erik [133]

Answer:

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Explanation:

The first high part is Q4, then the low part is Q7, the following high part is Q6, and the energy moving from the next two high points is Q5 because of the diagram.

5 0
2 years ago
What is the basic unit of chemistry?
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7 0
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If sugar contains 41.86% carbon and 6.98% hydrogen what % of sugar is oxygen
aleksklad [387]
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3 0
3 years ago
What is the name of the molecule that is used to heat most of our buildings?<br><br> (Chemistry)
mario62 [17]

Answer:

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Explanation:

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7 0
3 years ago
A certain first-order reaction has a half-life of 25.2 s at 20°C. What is the value of the rate constant k at 60°C if the activa
DochEvi [55]

Answer:

t

(

2

)

1/2

=

85.25 s

Notice how you're given the half-life (for one temperature), a second temperature, and the activation energy. The key to doing this problem is recognizing that:

the half-life for a first-order reaction is related to its rate constant.

the rate constant changes at different temperatures.

Go here for a derivation of the half-life of a first-order reaction. You should find that:

t

1/2

=

ln

2

k

Therefore, if we label each rate constant, we have:

k

1

=

ln

2

t

(

1

)

1/2

k

2

=

ln

2

t

(

2

)

1/2

Recall that the activation energy can be found in the Arrhenius equation:

k

=

A

e

−

E

a

/

R

T

where:

A

is the frequency factor, i.e. it is proportional to the number of collisions occurring over time.

E

a

is the activation energy in

kJ/mol

.

R

=

0.008314472 kJ/mol

⋅

K

is the universal gas constant. Make sure you get the units correct on this!

T

is the temperature in

K

(not

∘

C

).

Now, we can derive the Arrhenius equation in its two-point form. Given:

k

2

=

A

e

−

E

a

/

R

T

2

k

1

=

A

e

−

E

a

/

R

T

1

we can divide these:

k

2

k

1

=

e

−

E

a

/

R

T

2

e

−

E

a

/

R

T

1

Take the

ln

of both sides:

ln

(

k

2

k

1

)

=

ln

(

e

−

E

a

/

R

T

2

e

−

E

a

/

R

T

1

)

=

ln

(

e

−

E

a

/

R

T

2

)

−

ln

(

e

−

E

a

/

R

T

1

)

=

−

E

a

R

T

2

−

(

−

E

a

R

T

1

)

=

−

E

a

R

[

1

T

2

−

1

T

1

]

Now if we plug in the rate constants in terms of the half-lives, we have:

ln

⎛

⎜

⎝

ln

2

/

t

(

2

)

1/2

ln

2

/

t

(

1

)

1/2

⎞

⎟

⎠

=

−

E

a

R

[

1

T

2

−

1

T

1

]

This gives us a new expression relating the half-lives to the temperature:

⇒

ln

⎛

⎜

⎝

t

(

1

)

1/2

t

(

2

)

1/2

⎞

⎟

⎠

=

−

E

a

R

[

1

T

2

−

1

T

1

]

Now, we can solve for the new half-life,

t

(

2

)

1/2

, at the new temperature,

40

∘

C

. First, convert the temperatures to

K

:

T

1

=

25

+

273.15

=

298.15 K

T

2

=

40

+

273.15

=

313.15 K

Finally, plug in and solve. We should recall that

ln

(

a

b

)

=

−

ln

(

b

a

)

, so the negative cancels out if we flip the

ln

argument.

⇒

ln

⎛

⎜

⎝

t

(

2

)

1/2

t

(

1

)

1/2

⎞

⎟

⎠

=

E

a

R

[

1

T

2

−

1

T

1

]

⇒

ln

⎛

⎜

⎝

t

(

2

)

1/2

400 s

⎞

⎟

⎠

=

80 kJ/mol

0.008314472 kJ/mol

⋅

K

[

1

313.15 K

−

1

298.15 K

]

=

(

9621.78 K

)

(

−

1.607

×

10

−

4

K

−

1

)

=

−

1.546

Now, exponentiate both sides to get:

t

(

2

)

1/2

400 s

=

e

−

1.546

⇒

t

(

2

)

1/2

=

(

400 s

)

(

e

−

1.546

)

=

85.25 s

This should make sense, physically. From the Arrhenius equation, the higher

T

2

is, the more negative the

[

1

T

2

−

1

T

1

]

term, which means the larger the right hand side of the equation is.

The larger the right hand side gets, the larger

k

2

is, relative to

k

1

(i.e. if

ln

(

k

2

k

1

)

is very large,

k

2

>>

k

1

). Therefore, higher temperatures means larger rate constants.

Furthermore, the rate constant is proportional to the rate of reaction

r

(

t

)

in the rate law. Therefore...

The higher the rate constant, the faster the reaction, and thus the shorter its half-life should be.

Explanation:

Sorry just go here https://socratic.org/questions/588d14f211ef6b4912374c92#370588

3 0
2 years ago
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