If Ka for HBrO is 2. 8×10^−9 at 25°C, then the value of Kb for BrO− at 25°C is 3.5× 10^(-6).
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What is base dissociation constant?
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The base dissociation constant (Kb) is defined as the measurement of the ions which base can dissociate or dissolve in the aqueous solution. The greater the value of base dissociation constant greater will be its basicity an strength.
The dissociation reaction of hydrogen cyanide can be given as
HCN --- (H+) + (CN-)
Given,
The value of Ka for HCN is 2.8× 10^(-9)
The correlation between base dissociation constant and acid dissociation constant is
Kw = Ka × Kb
Kw = 10^(-14)
Substituting values of Ka and Kw,
Kb = 10^(-14) /{2.8×10^(-9) }
= 3.5× 10^(-6)
Thus, we find that if Ka for HBrO is 2. 8×10^−9 at 25°C, then the value of Kb for BrO− at 25°C is 3.5× 10^(-6).
DISCLAIMER: The above question have mistake. The correct question is given as
Question:
Given that Ka for HBrO is 2. 8×10^−9 at 25°C. What is the value of Kb for BrO− at 25°C?
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The answer is 34.1 mL.
Solution:
Assuming ideal behavior of gases, we can use the universal gas law equation
P1V1/T1 = P2V2/T2
The terms with subscripts of one represent the given initial values while for terms with subscripts of two represent the standard states which is the final condition.
At STP, P2 is 760.0torr and T2 is 0°C or 273.15K. Substituting the values to the ideal gas expression, we can now calculate for the volume V2 of the gas at STP:
(800.0torr * 34.2mL) / 288.15K = (760.0torr * V2) / 273.15K
V2 = (800.0torr * 34.2mL * 273.15K) / (288.15K * 760.0torr)
V2 = 34.1 mL
They will melt at the same rate because they contain the same matter
hope this helps and good luck on your project!!!!
Answer:
All of the above processes have a ΔS < 0.
Explanation:
ΔS represents change in entropy of a system. Entropy refers to the degree of disorderliness of a system.
The question requests us to identify the process that has a negative change of entropy.
carbon dioxide(g) → carbon dioxide(s)
There is a change in state from gas to solid. Solid particles are more ordered than gas particles so this is a negative change in entropy.
water freezes
There is a change in state from liquid to solid. Solid particles are more ordered than liquid particles so this is a negative change in entropy.
propanol (g, at 555 K) → propanol (g, at 400 K)
Temperature is directly proportional to entropy, this means higher temperature leads t higher entropy.
This reaction highlights a drop in temperature which means a negative change in entropy.
methyl alcohol condenses
Condensation is the change in state from gas to liquid. Liquid particles are more ordered than gas particles so this is a negative change in entropy.
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