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snow_tiger [21]
3 years ago
9

5 drops of 0.15 M Ki added to40 drops of Na2S2O3What is the final concentration of ki?​

Chemistry
1 answer:
rjkz [21]3 years ago
3 0

Answer:

\boxed{\text{0.017 mol/L}}

Explanation:

Na₂S₂O₃ solution does not react with KI (it reacts with I₂), so it is simply diluting the KI, and we can use the dilution formula.

c_{1}V_{1} = c_{2}V_{2}

Data:

c₁ = 0.15 mol·L⁻¹; V₁ = 5 drops

V(Na₂S₂O₃) = 40 drops

Calculations:

(a) Calculate the total volume

V₂ = 5 + 40 = 45 drops

(b) Calculate the concentration

0.15 × 5 = c₂ × 45

0.75 = 45c₂

c_{2} = \dfrac{0.75 }{45} = \boxed{\textbf{0.017 mol/L}}

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A 3.82L balloon filled with gas is warmed from 204.9K to 304.8 K.
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1. The heat of fusion for the ice-water phase transition is 335 kJ/kg at 0°C and 1 bar. The density of water is 1000 kg/m3 at th
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Answer:

Expression for the change of melting temperature with pressure..> T₂ = T₁exp(-(P₂-P₁)/(3.61x10⁹ Pa), Freezing Point = 0°C

Explanation:

Derivation from state postulate

Using the state postulate, take the specific entropy,  , for a homogeneous substance to be a function of specific volume  and temperature  .

ds = (partial s/partial v)(t) dv + (partial s/partial T)(v) dT

During a phase change, the temperature is constant, so

ds = (partial s/partial v)(T)  dv

Using the appropriate Maxwell relation gives

ds = (partial P/partial T)(v) dv

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dP/dT = s(β) – s(α)/v(β) – v(α) = Δs/Δv

Here Δs and Δv are respectively the change in specific entropy and specific volume from the initial phase α to the final phase β.

For a closed system undergoing an internally reversible process, the first law is

du = δq – δw = Tds - Pdv

Using the definition of specific enthalpy, h and the fact that the temperature and pressure are constant, we have

du + Pdv = dh Tds,

ds = dh/T,

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After substitution of this result into the derivative of the pressure, one finds

dp/dT = L/TΔv

<u>This last equation is the Clapeyron equation.</u>

a)

(dP/dT) = dH/TdV => dP/dlnT = dH/dV

=> dP/dlnT = dH/dV = [H(liquid) - H(solid)]/[V(liquid) - V(solid)]

= [335,000 J/kg]/[1000⁻¹ - 915⁻¹ m³/kg]

= -3.61x10⁹ J/m³ = -3.61x10⁹ Pa

=> P₂ = P₁ - 3.61x10⁹ ln(T₂/T₁) Pa

or

T₂ = T₁exp(-(P₂-P₁)/(3.61x10⁹ Pa)

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T₂(freezing) = 273.15exp[-(84,600-100,000)/(3.61x10⁹)]

≅ 273.15 = 0°C T₁(freezing) essentially no change

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