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qwelly [4]
3 years ago
14

A balloon containing helium gas expands from 230 mL to 860 mL as more helium is added. What was the initial quantity of helium p

resent if the expanded balloon contains 3.8 × 10-4 mol, assuming constant temperature and pressure? Which of the variables are known?
Chemistry
2 answers:
irina1246 [14]3 years ago
7 0
Using the Ideal Gas Law:

pV=nRT\iff n=\dfrac{pV}{RT}

Calculating the ratio between the initial and the final numbers of moles:

\dfrac{n_1}{n_2}=\dfrac{\dfrac{p_1V_1}{RT_1}}{\dfrac{p_2V_2}{RT_2}}

The statement says that T_1=T_2,~p_1=p_2. Hence:

\dfrac{n_1}{n_2}=\dfrac{V_1}{V_2}\iff \dfrac{n_1}{3.8\times10^{-4}}=\dfrac{230}{860}\iff\\\\ n_1=\dfrac{3.8\times10^{-4}\times230}{860}\iff\boxed{n_1\approx1.0\times10^{-4}~mol}
dlinn [17]3 years ago
3 0

beginning volume and ending quantity of gas

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The question is incomplete. Complete question is attached below
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Correct Answer: Option C i.e. I ~ III < IV < V < II

Reason:
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Order of reactivity, during such reactions depends on the electron density on carbon atom that is attached to Cl. Lower the electron density, greater will be the reactivity.

Among the provided chloroarenes, electron density on C atom will be minimum in case of compound II, because of presence of electron withdrawing group (-NO2) at ortho and para position. Due to this, there will be large number of resonating structures. This signifies greater electron de-localization, and hence largest reactivity for nucleophilic substitution reaction.

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