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vladimir1956 [14]
3 years ago
12

Which of the following would have the largest pKa?

Chemistry
1 answer:
garri49 [273]3 years ago
5 0

Answer:

CH3CH2NH3+/CH3CH2NH2 would have the largest pKa

Explanation:

To answer this question we must know Kb of CH3CH2NH2 is 5.6x10⁻⁴, and for C6H5NH2 is 4.0x10⁻¹⁰. And the CH3CH2NH3+ and C6H5NH3+ are related with these substances because are their conjugate base. That means:

pKa of  CH3CH2NH3+ =  CH3CH2NH2;  C6H5NH3+ =  C6H5NH2

Also, Kw / Kb = Ka

Thus:

pKa of CH3CH2NH3+/CH3CH2NH2 is:

Kw / kb = Ka = 1.79x10⁻¹¹

-log Ka = pKa

pKa = 10.75

pKa of C6H5NH3+/ C6H5NH2 is:

Kw / kb = Ka = 2.5x10⁻⁵

-log Ka = pKa

pKa = 4.6

That means CH3CH2NH3+/CH3CH2NH2 would have the largest pKa

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Answer:

A is the correct answer.

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Which of the following is not a property of a buffer solution? a) It is a mixture of a weak acid and its conjugate base. b) Resi
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Answer:

e) pH is independent of concentration.

Explanation:

a) It is a mixture of a weak acid and its conjugate base. <em>TRUE. </em>A buffer is defined as a mixture of a weak acid and its conjugate base or a weak base and its conjugate acid.

b) Resists pH changes because it reacts with added acid or base. <em>TRUE. </em>Thermodynamically, the reaction of added acid or base is faster with the buffer mixture than with H⁺ or OH⁻ ions of the solutions.

c) The maximum buffer capacity is at pH = pKa. <em>TRUE. </em>The buffer capacity is pka±1. For this, buffer capacity is maximum in pka.

d) pH is dependent on the solution ionic strength and temperature. <em>TRUE.</em> Ionic strength and temperature are factors that influence concentrations of ions in solutions as the H⁺ ion that is the responsible

e) pH is independent of concentration. <em>FALSE. </em>pH in a buffer depends completely of concentrations of the acid and its conjugate base or vice versa.

I hope it helps!

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