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Licemer1 [7]
3 years ago
13

If you mix 95 degrees C and 5 degrees C what temperature would you get?

Chemistry
1 answer:
forsale [732]3 years ago
4 0

Answer:

Between 5^oC and 95^oC

Explanation:

According to the second law of thermodynamics, heat flows from hotter objects toward colder objects.

Having a mixture of two components, one at a higher temperature of 95^oC and the other one at a lower temperature of 5^oC, heat will flow from the first object to the second one.

The temperature of the first object will decrease and the temperature of the second object will increase. Assuming no phase change, the final equilibrium temperature will be reached between 5^oC and 95^oC.

We cannot tell the exact temperature, unless we know the specific heat capacity of each material and their masses. The first object will give off heat given by:

Q_1 = c_1m_1(95^oC - t_f)

The second object will gain this heat by:

Q_2 = c_2m_2(t_f - 5^oC)

Since the heat given off is equal to the heat gained:

c_1m_1(95^oC - t_f) = c_2m_2(t_f - 5^oC)

Let's say that each object is water with a specific heat capacity of:

c_1 = c_2 = 4.184 \frac{J}{g^oC}

The mass of the first object is 10 g, the mass of the second one is 50 g, then:

4.184 \frac{J}{g^oC}\cdot 10 g\cdot (95^oC - t_f) = 4.184 \frac{J}{g^oC}\cdot 50 g\cdot (t_f - 5^oC)

The equation is simplified to:

950 - 10t_f = 50t_f - 250

60t_f = 1200

t_f = 20^oC

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3 years ago
A standard solution of FeSCN2+ is prepared by combining 9.0 mL of 0.20 M Fe(NO3)3 with 1.0 mL of 0.0020 M KSCN . The standard so
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Answer : The equilibrium concentration of SCN^- in the trial solution is 4.58\times 10^{-8}M

Explanation :

First we have to calculate the initial moles of Fe^{3+} and SCN^-.

\text{Moles of }Fe^{3+}=\text{Concentration of }Fe^{3+}\times \text{Volume of solution}

\text{Moles of }Fe^{3+}=0.20M\times 9.0mL=1.8mmol

and,

\text{Moles of }SCN^-=\text{Concentration of }SCN^-\times \text{Volume of solution}

\text{Moles of }SCN^-=0.0020M\times 1.0mL=0.0020mmol

The given balanced chemical reaction is,

Fe^{3+}(aq)+SCN^-(aq)\rightleftharpoons FeSCN^{2+}(aq)

Since 1 mole of Fe^{3+} reacts with 1 mole of SCN^- to give 1 mole of FeSCN^{2+}

The limiting reagent is, SCN^-

So, the number of moles of FeSCN^{2+} = 0.0020 mmole

Now we have to calculate the concentration of FeSCN^{2+}.

\text{Concentration of }FeSCN^{2+}=\frac{0.0020mmol}{9.0mL+1.0mL}=0.00020M

Using Beer-Lambert's law :

A=\epsilon \times C\times l

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A = absorbance of solution

C = concentration of solution

l = path length

\epsilon = molar absorptivity coefficient

\epsilon and l are same for stock solution and dilute solution. So,

\epsilon l=\frac{A}{C}=\frac{0.480}{0.00020M}=2400M^{-1}

For trial solution:

The equilibrium concentration of SCN^- is,

[SCN^-]_{eqm}=[SCN^-]_{initial}-[FeSCN^{2+}]

[SCN^-]_{initial} = 0.00050 M

Now calculate the [FeSCN^{2+}].

C=\frac{A}{\epsilon l}=\frac{0.220}{2400M^{-1}}=9.17\times 10^{-5}M

Now calculate the concentration of SCN^-.

[SCN^-]_{eqm}=[SCN^-]_{initial}-[FeSCN^{2+}]

[SCN^-]_{eqm}=(0.00050M)-(9.17\times 10^{-5}M)

[SCN^-]_{eqm}=4.58\times 10^{-8}M

Therefore, the equilibrium concentration of SCN^- in the trial solution is 4.58\times 10^{-8}M

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