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sashaice [31]
3 years ago
12

For the reaction 2Co3+(aq)+2Cl−(aq)→2Co2+(aq)+Cl2(g). E∘=0.483 V what is the cell potential at 25 ∘C if the concentrations are [

Co3+]= 0.190 M , [Co2+]= 0.205 M , and [Cl−]= 0.144 M , and the pressure of Cl2 is PCl2= 7.30 atm ?
Chemistry
1 answer:
Nesterboy [21]3 years ago
6 0

Answer:

Ecel =0,04 V

Explanation:

Apply the Nerst equation,

Ecel= Ecelº - (RT/nF)*lnQ

where R=8,314 J/molK, T=25ºC=298K and F =96 485 Coulombs/mol e- and n=number of moles of electrons transferred in the balanced equation. Q is cocient of products and reactives power to respective coefficients, if is a gas apply partial pressure

Write the semiequation redox and verify the numbers of electron for balance. In this case you don't need to change nothing

2Cl−(aq)→Cl2(g) + 2e-

<u>2CO3+(aq) + 2e-→2CO2+(aq)</u>

2Cl−(aq) + <u>2CO3+(aq) </u>→<u>2CO2+(aq) + </u>Cl2(g)

Hence

Ecel= 0.483 V -  0.013Ln ([CO2+]^2*PCl2] / [CO3+]^2*[Cl-]^2)

Ecel= 0.483 V -  0.013Ln ([0.205]^2 * 7.3] / [0.19]^2*[0.144]^2)

Ecel =0,04 V

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So your solution has

[

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−−−−−−−−−−−−−−−−−−−−

In your case, you have

pOH

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−−−−−−−−−−−−−−so you can't use

pH

=

−

log

(

0.150

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because that's the concentration of the hydroxide anions,

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−

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3

O

+

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pOH

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pH

.

Sodium hydroxide is a strong base, which means that it dissociates completely in aqueous solution to produce hydroxide anions in a

1

:

1

mole ratio.

NaOH

(

a

q

)

→

Na

+

(

a

q

)

+

OH

−

(

a

q

)

So your solution has

[

OH

−

]

=

[

NaOH

]

=

0.150 M

Now, the

pOH

of the solution can be calculated by using

pOH

=

−

log

(

[

OH

−

]

)

−−−−−−−−−−−−−−−−−−−−

In your case, you have

pOH

=

−

log

(

0.150

)

=

0.824

Now, an aqueous solution at

25

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2 years ago
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nikklg [1K]

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Explanation:

To calculate the disintegrations per second as -

Given ,

2.31 μCi of sulfur  -35 .

Since ,

1 Ci = 3.7 * 10 ¹⁰ Bq

1 μCi = 10 ⁻⁶ Ci

Hence ,

conversation is done as follows -

2.31 ( 1 * 10⁻⁶) * ( 3.7 * 10¹⁰)

= 8.547 x 10⁴

Hence ,

8.547 x 10⁴disintegrations per second , the sample undergo for it to be brand new .

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