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kogti [31]
3 years ago
6

Ba(OH)2 Ba+2 + 2 OH- (dissolved in solution). Which will NOT happen to the equilibrium of this solution as H+ ions are added? H+

will combine with OH- to form water. The base will dissociate to form more OH-. The reaction will move to the right. The reaction will move to the left. The quantity of Ba(OH)2 will decrease.
Chemistry
1 answer:
prohojiy [21]3 years ago
5 0

Answer:

The reaction will move to the left.

Explanation:

  • For the reaction:

<em>Ba(OH)₂ = Ba²⁺ + 2OH⁻,</em>

<em>Ba(OH)₂ is dissociated to Ba²⁺ and 2OH⁻.</em>

  • If H⁺ ions are added to the equilibrium:

H⁺ will combine with OH⁻ to form water.

<em>So, the concentration of OH⁻ will decrease and the equilibrium is disturbed.</em>

<em />

<em>According to Le Châtelier's principle: </em>when there is an dynamic equilibrium, and this equilibrium is disturbed by an external factor, the equilibrium will be shifted in the direction that can cancel the effect of the external factor to reattain the equilibrium.

  • So, the reaction will move to the right to suppress the effect of decreasing OH⁻ concentration.

  • The base will dissociate to form more OH⁻ and thus, the quantity of Ba(OH)₂ will decrease.

<em>So, the right choice is: the reaction will move to the left, is the choice that will not happen to the equilibrium.</em>

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Explanation:

pH and pOH.....

The pH is a way of expressing the hydrogen ion concentration.

pH = -log[H+] ............. where [x] means "the concentration of x in moles per liter."

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When taking the log of a number, only the digits to the right of the decimal reflect the precision in the original number. Since 2.6x10^-6 has two significant digits, a pH of 5.59 has two significant digits.

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We can also use the H+ ion concentration to get the hydroxide ion concentration and from that the pOH.

Kw = [H+][OH-] = 1.00x10^-14 .......... at 25C .... like any Kc, the value changes with temperature

[OH-] = Kw / [H+] = 1.00x10^-14 / 2.6x10^-6 = 3.846x10^-9 .... to a couple of guard digits

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=========

Just for grins, you might want to know how Kw changes with temperature, and how [H+] and [OH-] are related at some other temperatures. The pH is the pH of a neutral solution at various temperatures. For instance at 10C a neutral solution has a pH of 7.27. That's not a basic pH. 7.27 is the pH of a neutral solution, but at a different temperature. In a neutral solution at 10C [H+] = [OH-] = 5.41x10^-8M.

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T .........pH ......... Kw

0......... 7.47....... 0.114 x 10-14

10....... 7.27....... 0.293 x 10-14

20....... 7.08....... 0.681 x 10-14

25....... 7.00....... 1.008 x 10-14

30....... 6.92....... 1.471 x 10-14

40....... 6.77....... 2.916 x 10-14

50....... 6.63....... 5.476 x 10-14

100..... 6.14....... 51.3 x 10-14

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