Answer:
A. ΔG° = 132.5 kJ
B. ΔG° = 13.69 kJ
C. ΔG° = -58.59 kJ
Explanation:
Let's consider the following reaction.
CaCO₃(s) → CaO(s) + CO₂(g)
We can calculate the standard enthalpy of the reaction (ΔH°) using the following expression.
ΔH° = ∑np . ΔH°f(p) - ∑nr . ΔH°f(r)
where,
n: moles
ΔH°f: standard enthalpy of formation
ΔH° = 1 mol × ΔH°f(CaO(s)) + 1 mol × ΔH°f(CO₂(g)) - 1 mol × ΔH°f(CaCO₃(s))
ΔH° = 1 mol × (-635.1 kJ/mol) + 1 mol × (-393.5 kJ/mol) - 1 mol × (-1206.9 kJ/mol)
ΔH° = 178.3 kJ
We can calculate the standard entropy of the reaction (ΔS°) using the following expression.
ΔS° = ∑np . S°p - ∑nr . S°r
where,
S: standard entropy
ΔS° = 1 mol × S°(CaO(s)) + 1 mol × S°(CO₂(g)) - 1 mol × S°(CaCO₃(s))
ΔS° = 1 mol × (39.75 J/K.mol) + 1 mol × (213.74 J/K.mol) - 1 mol × (92.9 J/K.mol)
ΔS° = 160.6 J/K. = 0.1606 kJ/K.
We can calculate the standard Gibbs free energy of the reaction (ΔG°) using the following expression.
ΔG° = ΔH° - T.ΔS°
where,
T: absolute temperature
<h3>A. 285 K</h3>
ΔG° = ΔH° - T.ΔS°
ΔG° = 178.3 kJ - 285K × 0.1606 kJ/K = 132.5 kJ
<h3>B. 1025 K</h3>
ΔG° = ΔH° - T.ΔS°
ΔG° = 178.3 kJ - 1025K × 0.1606 kJ/K = 13.69 kJ
<h3>C. 1475 K</h3>
ΔG° = ΔH° - T.ΔS°
ΔG° = 178.3 kJ - 1475K × 0.1606 kJ/K = -58.59 kJ
3Zn + 8HNO₃⇒ 3Zn(NO₃)₂ + 2NO + 4H₂O
<h3>Further explanation
</h3>
Equalization of chemical reaction equations can be done using variables. Steps in equalizing the reaction equation:
- 1. gives a coefficient on substances involved in the equation of reaction such as a, b, or c etc.
- 2. make an equation based on the similarity of the number of atoms where the number of atoms = coefficient × index between reactant and product
- 3. Select the coefficient of the substance with the most complex chemical formula equal to 1
For gas combustion reaction which is a reaction of hydrocarbons with oxygen produces CO₂ and H₂O (water vapor). can use steps:
Balancing C atoms, H and the last O atoms
Reaction
Zn + HNO₃⇒ Zn(NO₃)₂ + NO + H₂O
aZn + bHNO₃⇒ Zn(NO₃)₂ + cNO + dH₂O
Zn : left = a, right =1 ⇒a=1
H : left = b, right = 2d⇒ b=2d (eq 1)
N : left = b, right = 2+c⇒b=2+c (eq 2)
O : left = 3b, right = 6+c+d ⇒3b=6+c+d(eq 3)
3(2d)=6+c+d
6d=6+c+d
5d=6+c (eq 4)
3(2+c)=6+c+d
6+3c=6+c+d
2c=d (eq 5)
5(2c)=6+c
10c=6+c
9c=6
c = 2/3
d = 2 x 2/3
d = 4/3
b = 2 x 4/3
b = 8/3
The equation
aZn + bHNO₃⇒ Zn(NO₃)₂ + cNO + dH₂O to
Zn + 8/3HNO₃⇒ Zn(NO₃)₂ + 2/3NO + 4/3H₂O x 3
3Zn + 8HNO₃⇒ 3Zn(NO₃)₂ + 2NO + 4H₂O
Answer:
1.81 x 10²⁴ atoms
Explanation:
To find the number of atoms in the given number of moles, we need to understand that every substance contains the Avogadro's number of particles.
More appropriately, a mole of any substance will contain the Avogadro's number of particles which is 6.02 x 10²³ atoms
So;
If 1 mole of a substance = 6.02 x 10²³ atoms;
3 mole of MgCl₂ will contain 3 x 6.02 x 10²³ = 1.81 x 10²⁴ atoms
An atom is the smallest you can get to identify the element.
The citric acid cycle should be the answer.
