Answer:
aqueous acid is used as a reagent.
Explanation:
Addition of Grignard reagent in aldehyde and followed by the acidification give rise to the primary or secondary alcohol. when the formaldehyde is used than the primary alcohol is formed otherwise secondary alcohol is formed.
in this reaction we also use the aqueous acid for the acidification as a reagent. We add aqueous acid when ethanol is present. This is because ethanol is get converted in the presence of aqueous acid into the chloroethane.
The hydrogen bonding in H₂O is stronger than that of HF
Explanation:
Hydrogen bonds are special dipole-dipole attraction in which electrostatic attraction is established between hydrogen atom of one molecule and the electronegative atom of a neighboring molecule.
- The strength of hydrogen bonds depends on the how electronegative an atom is.
- Electronegativity refers to the tendency of an atom to gain electrons.
- The higher the value, the higher the tendency.
- This why oxygen with a higher electronegativity will form a stronger hydrogen bond with hydrogen compared to fluorine.
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The number of mole of HCl needed for the solution is 1.035×10¯³ mole
<h3>How to determine the pKa</h3>
We'll begin by calculating the pKa of the solution. This can be obtained as follow:
- Equilibrium constant (Ka) = 2.3×10¯⁵
- pKa =?
pKa = –Log Ka
pKa = –Log 2.3×10¯⁵
pKa = 4.64
<h3>How to determine the molarity of HCl </h3>
- pKa = 4.64
- pH = 6.5
- Molarity of salt [NaZ] = 0.5 M
- Molarity of HCl [HCl] =?
pH = pKa + Log[salt]/[acid]
6.5 = 4.64 + Log[0.5]/[HCl]
Collect like terms
6.5 – 4.64 = Log[0.5]/[HCl]
1.86 = Log[0.5]/[HCl]
Take the anti-log
0.5 / [HCl] = anti-log 1.86
0.5 / [HCl] = 72.44
Cross multiply
0.5 = [HCl] × 72.44
Divide both side by 72.44
[HCl] = 0.5 / 72.4
[HCl] = 0.0069 M
<h3>How to determine the mole of HCl </h3>
- Molarity of HCl = 0.0069 M
- Volume = 150 mL = 150 / 1000 = 0.15 L
Mole = Molarity x Volume
Mole of HCl = 0.0069 × 0.15
Mole of HCl = 1.035×10¯³ mole
<h3>Complete question</h3>
How many moles of HCl need to be added to 150.0 mL of 0.50 M NaZ to have a solution with a pH of 6.50? (Ka of HZ is 2.3 x 10 -5 .) Assume negligible volume of the HCl
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