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erma4kov [3.2K]
4 years ago
13

FCalculate the pH of 1.00 X 10^-6 M HCI *​

Chemistry
1 answer:
amid [387]4 years ago
5 0

Explanation:

A.ph 6 B. correct ph goes in a scale up to 14 below 7 is acidic above 7 is basic and in the middle is newtral when they say pH they are asking how acidic is it when they ask for pOH they are asking how basic it is pH is calculated using logs as is pOH so ans

12.65

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Calculate the standard reaction Gibbs free energy for the following cell reactions: (a) 2 Ce41(aq) 1 3 I2(aq) S 2 Ce31(aq) 1 I32
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<u>Answer:</u>

<u>For a:</u> The standard Gibbs free energy of the reaction is -347.4 kJ

<u>For b:</u> The standard Gibbs free energy of the reaction is 746.91 kJ

<u>Explanation:</u>

Relationship between standard Gibbs free energy and standard electrode potential follows:

\Delta G^o=-nFE^o_{cell}           ............(1)

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The given chemical equation follows:

2Ce^{4+}(aq.)+3I^{-}(aq.)\rightarrow 2Ce^{3+}(aq.)+I_3^-(aq.)

<u>Oxidation half reaction:</u>   Ce^{4+}(aq.)\rightarrow Ce^{3+}(aq.)+e^-       ( × 2)

<u>Reduction half reaction:</u>   3I^_(aq.)+2e^-\rightarrow I_3^-(aq.)

We are given:

n=2\\E^o_{cell}=+1.08V\\F=96500

Putting values in equation 1, we get:

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Hence, the standard Gibbs free energy of the reaction is -347.4 kJ

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The given chemical equation follows:

6Fe^{3+}(aq.)+2Cr^{3+}+7H_2O(l)(aq.)\rightarrow 6Fe^{2+}(aq.)+Cr_2O_7^{2-}(aq.)+14H^+(aq.)

<u>Oxidation half reaction:</u>   Fe^{3+}(aq.)\rightarrow Fe^{2+}(aq.)+e^-       ( × 6)

<u>Reduction half reaction:</u>   2Cr^{2+}(aq.)+7H_2O(l)+6e^-\rightarrow Cr_2O_7^{2-}(aq.)+14H^+(aq.)

We are given:

n=6\\E^o_{cell}=-1.29V\\F=96500

Putting values in equation 1, we get:

\Delta G^o=-6\times 96500\times (-1.29)=746,910J=746.91kJ

Hence, the standard Gibbs free energy of the reaction is 746.91 kJ

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