Nitrogen and oxygen are in unpolluted air
The fifth shell can hold up to 50 electrons and the forth shell can hold 8 electrons
Total of 127.013 C of charge is passed
Given
weight of Ag solution before current has passed = 1.7854 g
weight of Ag solution after current has passed = 1.8016 g
Molecular mass of Ag = 107.86 g
Faraday's Constant = 96485
First of all we have to apply Faraday's First Law of Electrolysis i.e
m = ZQ
where
Z is propotionality constant (g/C)
Q is charge (C)
Hence,
Z = Atomic mass of substance/ Faraday's Constant
= 
= 0.0011178 g/C
Now ,
change in mass before and after the passing of current (Δm)
Δm = 1.8016g-1.7854g
= 0.0162g
Now amount of coulombs passed = 
amount of coulombs passed = 127.03524 C
Thus from the above conclusion we can say that amount of coulombs have passed is 127.03524 C
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As we know that Molarity is given as,
M = moles / V
Solving for V,
V = moles / M ------------------(1)
Also, moles is equal to,
moles = mass / M. mass -------------(2)
puting value of moles from eq. 2 into eq. 1,
V = (mass / M.mass) / M
Putting values,
V = (45 g / 164 g/mol) / 1.3 mol/dm³
V = 0.21 dm³