Which prototype is the most cost- and time-effective solution? The Rockets First company needs to hire an engineer to develop a
2 answers:
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Answer:
1. d[H₂O₂]/dt = -6.6 × 10⁻³ mol·L⁻¹s⁻¹; d[H₂O]/dt = 6.6 × 10⁻³ mol·L⁻¹s⁻¹
2. 0.58 mol
Explanation:
1.Given ΔO₂/Δt…
2H₂O₂ ⟶ 2H₂O + O₂
-½d[H₂O₂]/dt = +½d[H₂O]/dt = d[O₂]/dt
d[H₂O₂]/dt = -2d[O₂]/dt = -2 × 3.3 × 10⁻³ mol·L⁻¹s⁻¹ = -6.6 × 10⁻³mol·L⁻¹s⁻¹
d[H₂O]/dt = 2d[O₂]/dt = 2 × 3.3 × 10⁻³ mol·L⁻¹s⁻¹ = 6.6 × 10⁻³mol·L⁻¹s⁻¹
2. Moles of O₂
(a) Initial moles of H₂O₂
(b) Final moles of H₂O₂
The concentration of H₂O₂ has dropped to 0.22 mol·L⁻¹.
(c) Moles of H₂O₂ reacted
Moles reacted = 1.5 mol - 0.33 mol = 1.17 mol
(d) Moles of O₂ formed
Answer : The correct answer for a) 4-bromo-2-iodo-4-methyl pentane and b)5-bromo-2-ethoxy-2-methyl pentane.
A) Reaction with NaI :
Reaction of alkyl halide with NaI is known as Finkelstein Reaction . The acetone is used as solvent . It involves bimolecular nucleophillic substitution rmechanism (SN²) . There is replecement of one halogen with other occurs .
The incoming Nucleophile(Nu⁻) (halide) attacks on carbon from back side , while the leaving group (halide) leaves the compound from front side , simultaneously. The product so formed have is inverted .(Image)
NaI releases I⁻ ion which act as nucelophile and attacks on C1 carbon and Br⁻ from C1 carbon is released . Out of two bromines at C1 and C4 carbons , C1 is primary carbon which is less sterically hindered while C-4 is tertiary carbon and sterically hindered . So it is easy for incoming Nu⁻ to attack on C1 carbon .So Br⁻ is repleaced by I⁻.
1,4-dibromo-4-methylpentane + NaI → 4-bromo-1-iodo-4-methylpentane
The product formed from reaction between 1,4-dibromo-4-methylpentane and NaI is 4-bromo-1-iodo-4-methylpentane . (Image)
B) Reaction with AgNO3 :
Reaction of alkyl halide with AgNO3 in ethanol takes place via SN¹ ( unimolecular nucleophilic substitution ) mechanism . In this leaving group(halide) leaves from alkyl halide forming an intermediate carbocation species . The incoming Nu⁻ attack on this carbocation.
AgNO3 reacts releases Ag⁺ion which abstract Br⁻ of C-4 carbon from 1,4-dibromo-4-methylpentane. THis forms tertiary carbocation which is more stable than carbocation formed by removal of Br from C-1 . The ethanol being more Nucleophilic than NO₃⁻ (from AgNO₃), attacks on this carbocation .(Image )
The product formed as a result is 5-bromo-2-ethoxy-2-methyl pentane.
Answer : Option A) HF.
Explanation : Assuming the complete question as per the attachment.
H-F bonds are formed because of hydrogen bonding between H atom and F atom and is considered to be strongest amongst the rest other options given.
As given in the table it is clear that the molar mass of HF molecule is the lowest. It shows that, when dispersion increases in the molecule molecular weight also increases.
