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d1i1m1o1n [39]
3 years ago
5

Penn State Civil and Environmental Engineering Department just built a super-duper coal-fired power plant in Altoona, PA. It is

1,100 MW (i.e., large) with 40% efficiency. We used local coal that is 14,000 Btu/ pound. The sulfur content is 2%. We added a scrubber that is 65% efficient. A) How much sulfur will we release per hour (pounds/hour)? B) If all of the sulfur is oxidized to SO2 and the EPA insists on a 80% efficiency scrubber how much SO2 would be released (report value in pounds SO2/ kWh generated)?
Chemistry
1 answer:
Travka [436]3 years ago
8 0

Answer:

<u>Part -A:</u>

Sulfur released is 1.338 \times 10^{4}pounds/hour.

<u>Part-B:</u>

SO_{2} released of per EPA norms is 4.865 /times 10^{-3}P/kw.

Explanation:

From the given,

The output = 1100 Mw

Efficiency = η = 0.4

Substitute the values in the following

Input = Output / η

= \frac{1100}{0.4}= 2750 Mw

Let's converts between joules to BTU.

1 BTU = 1056 J

<u>Part-A;</u>

Energy\,\, required = Power \times time

2750 \times 10^{6} \,\, J/s \times 3600s = 9.9 \times 10^{12}J

Energy \,\, required = \frac{9.9 \times 10^{22}}{1056}= 9.375 \times 10^{9} BTU

Mass\,of\, coal\,required = \frac{9.375 \times 10^{9}}{14,000}=6.69 \times 10^{5}pounds

But it has 2%  sulfur

The mass of sulfur released

6.69 \times 10^{5}pounds \,coal \times 0.02 = 1.338 \times 10^{4}pound

Therefore, released sulfur is 1.338 \times 10^{4}pounds/hour.

<u>Part -B;</u>

One pound of sulfur produce two pounds of sulfur dioxide

Initial amount of produced sulfur =

2 \times 1.338 \times 10^{4}pound = 2.676\times 10^{4}pound/hour

Assuming we added a 80% efficiency then,

Released sulfur dioxide = (1-0.8) \times SO_{2} \,produced =0.2 \times 2.676 \times 10^{4}Pounds/hr= 5.352 \times 10^{3}Pounds/hr

Energy produced in an hour = 400 mw \times 1 hr = 1.1 \times 10^{6}kwh

SO_{2}\,released \, as \, per EPA = \frac{5.352 \times 10^{3} \,pounds}{1.1 \times 10^{6}kwh}= 4.865 \times 10^{-3}p\kwh

Therefore, SO_{2} released of per EPA norms is 4.865 /times 10^{-3}P/kw.

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Significant digits are numbers that helps to present the precision of measurements calculations.

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Carbon, helium, and sodium are monoatomic elements.

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antimony has two naturally occuring isotopes, sb121sb121 and sb123sb123 . sb121sb121 has an atomic mass of 120.9038 u120.9038 u
Luda [366]

Considering the definition of atomic mass, isotopes and atomic mass of an element, sb121 has a percent natural abundance of 0.5726 or 57.26% and sb123 has a percent natural abundance of 0.4284 or 42.84%.

<h3>Definition of atomic mass</h3>

The atomic mass is obtained by adding the number of protons and neutrons in a given nucleus of a chemical element.

<h3>Definition of isotope</h3>

Isotopes are the chemical elements in which atomic numbers are the same, but the number of neutrons is different.

<h3>Definition of atomic mass</h3>

The atomic mass of an element is the weighted average mass of its natural isotopes.

This is, the atomic masses of elements are usually calculated as the weighted average of the masses of the different isotopes of each element, considering the relative abundance of each of them.

<h3>Percent natural abundance of each isotope</h3>

In this case, antimony has two naturally occuring isotopes, sb121 and sb123. You know:

  • sb121 has an atomic mass of 120.9038 u.
  • sb121 has a percent natural abundance of x.
  • sb123 has an atomic mass of 122.9042 u.
  • sb123 has a percent natural abundance of 1 -x (or, what is the same, the abundance is 100% - x%, since both isotopes form 100% of the element.)
  • Antimony has an average atomic mass of 121.7601 u

The average mass of antimony is expressed as:

121.7601 u= 120.9038 u x + 122.9042 u× (1 -x)

Solving:

121.7601 u= 120.9038 u x + 122.9042 u - 122.9042 u x

121.7601 u - 122.9042 u= 120.9038 u x - 122.9042 u x

(-1.1441 u)= (-2.0014) x

(-1.1441 u)÷ (-2.0014)= x

<u><em>0.5726= x or 57.26%</em></u>

So, 1 -x= 1- 0.5716 → <u><em>1-x= 0.4284 or 42.84%</em></u>

<u><em /></u>

Finally, sb121 has a percent natural abundance of 0.5726 or 57.26% and sb123 has a percent natural abundance of 0.4284 or 42.84%.

Learn more about average atomic mass:

brainly.com/question/4923781

brainly.com/question/1826476

brainly.com/question/15230683

brainly.com/question/7955048

#SPJ1

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1 year ago
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