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Murljashka [212]
3 years ago
12

Over an interval of 3.00 s the average rate of change of the concentration of C was measured to be 0.0840 M/s. What is the final

concentration of D at the end of this same interval if its concentration was initially 3.000 M?
Chemistry
1 answer:
Harrizon [31]3 years ago
5 0

Answer:

Final Concentration = 3.252M

Explanation:

Let's bring out the data mentioned in the question.

Time, t = 3s

Rate = 0.0840 M/s

Initial Concentration = 3M

Final Concentration = x

The formular relating these parameters is;

Rate = ΔConcentration / ΔTime

Upon solving for ΔConcentration, we have;

ΔConcentration = Rate * ΔTime

ΔConcentration = 0.0840 * 3

ΔConcentration = 0.252

But ΔConcentration = Final Concentration - Initial Concentration

Hence,

Final Concentration = ΔConcentration + Initial Concentration

Final Concentration = 0.252 + 3

Final Concentration = 3.252M

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. Determine the standard free energy change, ɔ(G p for the formation of S2−(aq) given that the ɔ(G p for Ag+(aq) and Ag2S(s) are
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<u>Answer:</u> The standard free energy change of formation of S^{2-}(aq.) is 92.094 kJ/mol

<u>Explanation:</u>

We are given:

K_{sp}\text{ of }Ag_2S=8\times 10^{-51}

Relation between standard Gibbs free energy and equilibrium constant follows:

\Delta G^o=-RT\ln K

where,

\Delta G^o = standard Gibbs free energy = ?

R = Gas constant = 8.314J/K mol

T = temperature = 25^oC=[273+25]K=298K

K = equilibrium constant or solubility product = 8\times 10^{-51}

Putting values in above equation, we get:

\Delta G^o=-(8.314J/K.mol)\times 298K\times \ln (8\times 10^{-51})\\\\\Delta G^o=285793.9J/mol=285.794kJ

For the given chemical equation:

Ag_2S(s)\rightleftharpoons 2Ag^+(aq.)+S^{2-}(aq.)

The equation used to calculate Gibbs free change is of a reaction is:  

\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]

The equation for the Gibbs free energy change of the above reaction is:

\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]

We are given:

\Delta G^o_f_{(Ag_2S(s))}=-39.5kJ/mol\\\Delta G^o_f_{(Ag^+(aq.))}=77.1kJ/mol\\\Delta G^o=285.794kJ

Putting values in above equation, we get:

285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol

Hence, the standard free energy change of formation of S^{2-}(aq.) is 92.094 kJ/mol

8 0
3 years ago
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