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Constant Volume Calorimetry, also know as bomb calorimetry, is used to measure the heat of a reaction while holding volume constant and resisting large amounts of pressure. Although these two aspects of bomb calorimetry make for accurate results, they also contribute to the difficulty of bomb calorimetry. In this module, the basic assembly of a bomb calorimeter will be addressed, as well as how bomb calorimetry relates to the heat of reaction and heat capacity and the calculations involved in regards to these two topics.
Introduction
Calorimetry is used to measure quantities of heat, and can be used to determine the heat of a reaction through experiments. Usually a coffee-cup calorimeter is used since it is simpler than a bomb calorimeter, but to measure the heat evolved in a combustion reaction, constant volume or bomb calorimetry is ideal. A constant volume calorimeter is also more accurate than a coffee-cup calorimeter, but it is more difficult to use since it requires a well-built reaction container that is able to withstand large amounts of pressure changes that happen in many chemical reactions.
Most serious calorimetry carried out in research laboratories involves the determination of heats of combustion ΔHcombustion" role="presentation" style="display: inline-table; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">ΔHcombustionΔHcombustion, since these are essential to the determination of standard enthalpies of formation of the thousands of new compounds that are prepared and characterized each month. In a constant volume calorimeter, the system is sealed or isolated from its surroundings, and this accounts for why its volume is fixed and there is no volume-pressure work done. A bomb calorimeter structure consists of the following:
Steel bomb which contains the reactantsWater bath in which the bomb is submergedThermometerA motorized stirrerWire for ignition
is usually called a “bomb”, and the technique is known as bomb calorimetry
Another consequence of the constant-volume condition is that the heat released corresponds to qv , and thus to the internal energy change ΔUrather than to ΔH. The enthalpy change is calculated according to the formula
(1.1)ΔH=qv+ΔngRT" role="presentation" style="display: inline-table; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: center; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; width: 10000em !important; position: relative;">ΔH=qv+ΔngRT(1.1)(1.1)ΔH=qv+ΔngRT
Δng" role="presentation" style="display: inline-table; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">ΔngΔng is the change in the number of moles of gases in the reaction.
Answer:
V₂ = 530.5 mL
Explanation:
Given data:
Initial temperature = 20.0°C
Final temperature = 40.0 °C
Final volume = 585 mL
Initial volume = ?
Solution:
Initial temperature = 20.0°C (20+273 = 293 K)
Final temperature = 40.0 °C (40+273 = 323 K)
Solution:
The given problem will be solve through the Charles Law.
According to this law, The volume of given amount of a gas is directly proportional to its temperature at constant number of moles and pressure.
Mathematical expression:
V₁/T₁ = V₂/T₂
V₁ = Initial volume
T₁ = Initial temperature
V₂ = Final volume
T₂ = Final temperature
Now we will put the values in formula.
V₁/T₁ = V₂/T₂
V₁ = V₂T₁ /T₂
V₂ = 585 mL × 293 K / 323 K
V₂ = 171405 mL.K / 323 K
V₂ = 530.5 mL
Answer:
Number of moles = 0.0005 mol.
Explanation:
Given data:
pH = 3
Volume of solution = 500 mL
Number of moles = ?
Solution:
HCl dissociate to gives H⁺ and Cl⁻
HCl → H⁺ + Cl⁻
It is known that,
pH = -log [H⁺]
3 = -log [H⁺]
[H⁺] = 10⁻³ M
[H⁺] = 0.001 M
Number of moles of HCl:
Molarity = number of moles / Volume in litter
Number of moles = Molarity × Volume in litter
Number of moles = 0.001 mol/L × 0.5 L
Number of moles = 0.0005 mol
