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MAVERICK [17]
3 years ago
11

Materials expand when heated. Consider a metal rod of length L0 at temperature T0. If the temperature is changed by an amount ΔT

, then the rod’s length changes by ΔL=αL0ΔT, where α is the thermal expansion coefficient.
For steel, α=1.24×10−5∘C−1.(a) A steel rod has length L0=40cm at T0=40∘C. What is its length at T=180∘C?
(Use decimal notation. Give your answer to three decimal places.)
L≈cm
(b) Find its length at T=90∘C if its length at T0=120∘C is 65 in.
(Use decimal notation. Give your answer to three decimal places.)
L≈ in.
(c) Express length L as a function of T and α if L0=60in. at T0=150∘C.
(Use symbolic notation and fractions where needed.) L(T,α)=
Chemistry
1 answer:
marysya [2.9K]3 years ago
7 0

Answer:

(a) The length at temperature 180°C is 40.070 cm

(b) The length at temperature 90°C is 64.976 inches

(c) L(T, α) = 60·α·T - 9000·α + 60

Explanation:

(a) The given parameters are

The thermal expansion coefficient, α for steel = 1.24 × 10⁻⁵/°C

The initial length of the steel L₀ = 40 cm

The initial temperature, t₀ = 40°C

The length at temperature 180°C = L

Therefore, from the given relation, for change in length, ΔL, we have;

ΔL = α × L₀ × ΔT

The amount the temperature changed ΔT = 180°C - 40°C = 140°C

Therefore, the change in length, ΔL, is found as follows;

ΔL = α × L₀ × ΔT = 1.24 × 10⁻⁵/°C × 40 × 140°C = 0.07 cm

Therefore, L =  L₀ + ΔL = 40 + 0.07 = 40.07 cm

The length at temperature 180°C = 40.07 cm

(b) Given that the length at T = 120°C is 65 in., we have;

The temperature at which the new length is sought = 90°C

The amount the temperature changed ΔT = 90°C - 120°C = -30°C

ΔL = α × L₀ × ΔT = 1.24 × 10⁻⁵/°C × 65 × -30°C = -0.024375 inches

The length, L at 90°C is therefore, L = L₀ + ΔL = 65 - 0.024375 = 64.976 in.

The length at temperature 90°C = 64.976 inches

(c) L = L₀ + ΔL  = L₀ +  α × L₀ × ΔT = L₀ +  α × L₀ × (T - T₀)

Therefore;

L = 60 +  α × 60 × (T - 150°C)

L = 60 + α × 60 × T - 9000 × α

L(T, α) = 60·α·T - 9000·α + 60

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When nitrogen dioxide (NO2) from car exhaust combines with water in the air, it forms nitric acid (HNO3), which causes acid rain
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<u>Answer:</u>

<u>For a:</u> The number of molecules of nitrogen dioxide is 4.52\times 10^{23}

<u>For b:</u> The mass of nitric acid formed is 54.81 grams

<u>For c:</u> The mass of nitric acid formed is 206 grams

<u>Explanation:</u>

The given chemical reaction follows:

3NO_2(g)+H_2O(l)\rightarrow 2HNO_3(aq.)+NO(g)

  • <u>For a:</u>

By Stoichiometry of the reaction:

1 mole of water reacts with 3 moles of nitrogen dioxide

So, 0.250 moles of water will react with \frac{3}{1}\times 0.250=0.75mol of nitrogen dioxide

According to mole concept:

1 mole of a compound contains 6.022\times 10^{23} number of molecules.

So, 0.75 moles of nitrogen dioxide will contain 0.75\times 6.022\times 10^{23}=4.52\times 10^{23} number of molecules

Hence, the number of molecules of nitrogen dioxide is 4.52\times 10^{23}

  • <u>For b:</u>

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}     .....(1)

Given mass of nitrogen dioxide = 60.0 g

Molar mass of nitrogen dioxide = 46 g/mol

Putting values in equation 1, we get:

\text{Moles of nitrogen dioxide}=\frac{60.0g}{46g/mol}=1.304mol

By Stoichiometry of the reaction:

3 moles of nitrogen dioxide produces 2 mole of nitric acid

So, 1.304 moles of nitrogen dioxide will produce = \frac{2}{3}\times 1.304=0.870 moles of nitric acid

Now, calculating the mass of nitric acid from equation 1, we get:

Molar mass of nitric acid = 63 g/mol

Moles of nitric acid = 0.870 moles

Putting values in equation 1, we get:

0.870mol=\frac{\text{Mass of nitric acid}}{63g/mol}\\\\\text{Mass of nitric acid}=(0.870mol\times 63g/mol)=54.81g

Hence, the mass of nitric acid formed is 54.81 grams

  • <u>For c:</u>
  • <u>For nitrogen dioxide:</u>

Given mass of nitrogen dioxide = 225 g

Molar mass of nitrogen dioxide = 46 g/mol

Putting values in equation 1, we get:

\text{Moles of nitrogen dioxide}=\frac{225g}{46g/mol}=4.90mol

  • <u>For water:</u>

Given mass of water = 55.2 g

Molar mass of water = 18 g/mol

Putting values in equation 1, we get:

\text{Moles of water}=\frac{55.2g}{18g/mol}=3.06mol

By Stoichiometry of the reaction:

3 moles of nitrogen dioxide reacts with 1 mole of water

So, 4.90 moles of nitrogen dioxide will react with = \frac{1}{3}\times 4.90=1.63mol of water

As, given amount of water is more than the required amount. So, it is considered as an excess reagent.

Thus, nitrogen dioxide is considered as a limiting reagent because it limits the formation of product.

By Stoichiometry of the reaction:

3 mole of nitrogen dioxide produces 2 moles of nitric acid

So, 4.90 moles of nitrogen dioxide will produce \frac{2}{3}\times 4.90=3.27mol of nitric acid

Now, calculating the mass of nitric acid from equation 1, we get:

Molar mass of nitric acid = 63 g/mol

Moles of nitric acid = 3.27 moles

Putting values in equation 1, we get:

3.27mol=\frac{\text{Mass of nitric acid}}{63g/mol}\\\\\text{Mass of nitric acid}=(3.27mol\times 63g/mol)=206g

Hence, the mass of nitric acid formed is 206 grams

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3 years ago
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