First question. Applying ideal gas equation PV=nRT, P= 101.3 x 10³Pa = 1atm. therefore, 1 x 260 x 10^-3 = n x 0.082 x 294.( Temperature in kelvin=273+21). n = 0.01 moles. Volume of gas at STP= n x 22.4 = 0.01x22.4 = 0.224L. Hope this helps
Answer:
A) t = 22.5 min and B) t = 29.94 min
Explanation:
Initial concentration, [A]₀ = 100
Final concentration = 100 -75 = 25
Time = 45 min
A) First order reaction
ln[A] − ln[A]₀ = −kt
Solving for k;
ln[25] − ln[100] = - 45k
-1.386 = -45k
k = 0.0308 min-1
How long after its start will the reaction be 50% complete?
Initial concentration, [A]₀ = 100
Final concentration, [A] = 100 -50 = 50
Time = ?
ln[A] − ln[A]₀ = −kt
Solving for k;
ln[50] − ln[100] = - 0.0308 * t
-0.693 = -0.0308 * t
t = 22.5 min
B) Zero Order
[A] = [A]₀ − kt
Using the values from the initial reaction and solving for k, we have;
25 = 100 - k(45)
-75 = -45k
k = 1.67 M min-1
How long after its start will the reaction be 50% complete?
Initial concentration, [A]₀ = 100
Final concentration, [A] = 100 -50 = 50
Time = ?
[A] = [A]₀ − kt
50 = 100 - (1.67)t
-50 = - 1.67t
t = 29.94 min
BAS might be an improperly capitalized: BAs, BaS
PTF2 might be an improperly capitalized: PtF2
BAF2 might be an improperly capitalized: BaF2
PTS might be an improperly capitalized: PtS
DR is the correct answer
hope this helps