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Elena-2011 [213]
3 years ago
10

Calculate the boiling point of a 3.60 m aqueous sucrose solution. express the boiling point in degrees celsius to five significa

nt figures
Chemistry
2 answers:
kvv77 [185]3 years ago
8 0
We can use this equation for boiling point elevation:
ΔT(b) = i K(b) M
when Δ T(b) is the increase of boiling point of the solution.
and i is ( vant Hoff factor, the number of particles or ions per mole-clue.
and K(b) is boiling point increase constant for the solution ( and for water it is equal 0.52 C° Kg/mol)
We can assume i (vant Hoff factor ) = 1 as the sucrose is nonelectrolyte (not readily ionize).
So for water: Tb° = 100 c° and Kb = 0.52 c° Kg / mol
By substitute at:
ΔTb = i Kb M
∴  = 1 * 0.52 * 3.60 = 1.8432 C°
and when Tb = Tb° + ΔTb
∴  Tb = 100 + 1.8432 = 101.8432 C°



Alex3 years ago
7 0

Boiling point of 3.60 m aqueous sucrose solution is \boxed{101.87\text{ }^{\circ}\text{C}}.

Further Explanation:

Colligative properties are such properties that depend on number of solute particles only, but do not depend on identity of solute. Colligative properties are mentioned below.

1. Relative lowering of vapor pressure

2. Elevation in boiling point

3. Depression in freezing point

4. Osmotic pressure

The formula to calculate elevation in boiling point is as follows:

\Delta\text{T}_{\text{b}}=\text{k}_{\text{b}}\text{m}                                       ...... (1)

Where,

\Delta\text{T}_{\text{b}} is elevation in boiling point.

m is the molality of solution.

\text{k}_{\text{b}} is molal boiling point constant.

The value of m is 3.60 m.

The value of \text{k}_{\text{b}} is 0.512\text{ }^{\circ}\text{C/m}.

Substitute 3.60 m for m and 0.512\text{ }^{\circ}\text{C/m} for \text{k}_{\text{b}} in equation (1).

\begin{aligned}\Delta\text{T}_{\text{b}}&=(0.512\text{ }^{\circ}\text{C/m})(\text{3.60 m})\\&=1.872\text{ }^{\circ}\text{C}\end{aligned}

The boiling point elevation can also be calculated as follows:

\Delta\text{T}_{\text{b}}=\text{Boiling point of sucrose}-\text{Boiling point of pure water}      ...... (2)

Rearrange equation (2) for boiling point of sucrose.

\text{Boiling point of sucrose}=\Delta\text{T}_{\text{b}}+\text{Boiling point of pure water}      ...... (3)

The value of \Delta\text{T}_{\text{b}} is 1.872\text{ }^{\circ}\text{C}\end{aligned}.

The value of boiling point of pure water is 100\text{ }^{\circ}\text{C}\end{aligned}.

Substitute 1.872\text{ }^{\circ}\text{C}\end{aligned} for \Delta\text{T}_{\text{b}} and 100\text{ }^{\circ}\text{C}\end{aligned} for boiling point of pure water in equation (3).

\begin{aligned}\text{Boiling point of sucrose}&=1.872\text{ }^{\circ}\text{C}+100\text{ }^{\circ}\text{C}\\&=101.872\text{ }^{\circ}\text{C}\\&\approx{101.87\text{ }^{\circ}\text{C}}\end{aligned}

Learn more:

1. Which statement is true for Boyle’s law: brainly.com/question/1158880

2. Calculation of volume of gas: brainly.com/question/3636135

Answer details:

Grade: Senior School

Subject: Chemistry

Chapter: Colligative properties

Keywords: colligative properties, boiling point, osmoctic pressure, depression in freezing point, elevation in boiling point, relative lowering of vapor pressure, solute particles, sucrose, boiling point of sucrose, 3.60 m.

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agasfer [191]

Answer:

a. The limiting reactant is Ca(OH)₂

b. The theoretical yield of CaCl₂ is approximately 621.488 grams

c. The percentage yield of CaCl₂ is approximately 47.06%

Explanation:

a. The given chemical reaction is presented as follows;

Ca(OH)₂ + 2HCl → CaCl₂ + 2H₂O

Therefore;

One mole of Ca(OH)₂ reacts with two moles of HCl to produce one mole of CaCl₂ and two moles of water H₂O

The mass of HCl in an experiment, m₁ = 229.70 g

The mass of Ca(OH)₂ in an experiment, m₂ = 207.48 g

The molar mass of HCl, MM₁ = 36.458 g/mol

The molar mass of Ca(OH)₂, MM₂ =74.093 g/mol

The number of moles of HCl, present, n₁ = m₁/MM₁

∴ n₁ = m₁/MM₁ = 229.70 g/(36.458 g/mol) ≈ 6.3 moles

The number of moles of Ca(OH)₂, present, n₂ = m₂/MM₂

∴ n₂ = m₂/MM₂ = 207.48 g/(74.093 g/mol) ≈ 2.8 moles

The number of moles of Ca(OH)₂, present, n₂ = 2.8 moles

According the chemical reaction equation the number of moles of HCl the 2.8 moles of Ca(OH)₂ will react with, = 2.8 × 2 moles = 5.6 moles of HCl

Therefore, there is an excess HCl in the reaction and Ca(OH)₂ is the limiting reactant

b. According the chemical reaction equation the number of moles of CaCl₂ produced in he reaction by the 2.8 moles of Ca(OH)₂ = 2.8 × 2 moles = 5.6 moles of CaCl₂

The molar mass of CaCl₂ = 110.98 g/mol

The mass of the 5.6 moles of CaCl₂ = 5.6 moles × 110.98 g/mol ≈ 621.488 grams

The theoretical yield of CaCl₂ ≈ 621.488 grams

c. Given that the actual mass of CaCl₂ produced = 292.5 grams, we have;

The percentage yield of CaCl₂ = The actual yield/(The theoretical yield) × 100

∴ The percentage yield of CaCl₂ = (292.5 g)/(621.488 g) × 100 ≈ 47.0644646397%

The percentage yield of CaCl₂ ≈ 47.06%.

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