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Andrej [43]
3 years ago
7

Dehydration of 2-methyl-2-pentanol forms one major and one minor organic product. Draw the structures of the two organic product

s of this reaction.
Chemistry
1 answer:
Korvikt [17]3 years ago
7 0

Answer:

The major product is 2-methyl-2-pentene [ CH₃-CH₂-CH=C(CH₃)₂ ] and a minor product 2-methyl-1-pentene [ CH₃-CH₂-CH₂-C(CH₃)=CH₂ ].

Explanation:

Dehydration reaction is a reaction in which a molecule loses a water molecule in the presence of a dehydrating agent like sulfuric acid (H₂SO₄).

<u>Dehydration reaction of 2-methyl-2-pentanol</u> gives a major product 2-methyl-2-pentene and a minor product 2-methyl-1-pentene.

CH₃-CH₂-CH₂-C(CH₃)₂-OH (2-methyl-2-pentanol)→ CH₃-CH₂-CH=C(CH₃)₂ (2-methyl-2-pentene, major) + CH₃-CH₂-CH₂-C(CH₃)=CH₂ (2-methyl-1-pentene, minor)

<u>Since more substituted alkene is more stable than the less substituted alkene. So, the trisubstituted alkene, 2-methyl-2-pentene is more stable than the disubstituted alkene, 2-methyl-1-pentene.</u>

<u>Therefore, the trisubstituted alkene, 2-methyl-2-pentene is the major product and the disubstituted alkene, 2-methyl-1-pentene is the minor product.</u>

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Explanation: For the calculation of % ionic character, we use the formula

\% \text{ ionic character}= [1-e^{\frac{-(X_A-X_B)^2)}{4}}]\times(100\%)

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The table attached has the values of electronegativities, by taking the values of Al and Mn from there,

X_{Al}=1.61

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Putting the values in the electronegativity formula, we get

\% \text{ ionic character}= [1-e^{\frac{-(1.61-1.55)^2)}{4}}]\times(100\%)

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Now, there are 3 types of inter atomic bonding

1) Ionic Bonding: It refers to the chemical bond in which there is complete transfer of valence electrons between atoms

2) Covalent Bonding: It refers to the chemical bond involving the sharing of electron pairs between 2 atoms.

3) Metallic Bonding: It refers to the chemical bond in which there is an electrostatic force between the positively charged metal ions and delocalised electrons.

In Al_6Mn compound, the % ionic character is minimal that is \sim0.20% and there are two metal ions present, therefore this compound will have metallic bonding.

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