Answer : The initial rate of the reaction is, 
Explanation :
First we have to calculate the rate constant of the reaction.
Expression for rate law for first order kinetics is given by :
![k=\frac{2.303}{t}\log\frac{[A_o]}{[A]}](https://tex.z-dn.net/?f=k%3D%5Cfrac%7B2.303%7D%7Bt%7D%5Clog%5Cfrac%7B%5BA_o%5D%7D%7B%5BA%5D%7D)
where,
k = rate constant = ?
t = time taken for the process = 44 s
= initial amount or concentration of the reactant = 0.1108 M
= amount or concentration left time 44 s = 0.0554 M
Now put all the given values in above equation, we get:


Now we have to calculate the initial rate of the reaction.
Initial rate = K [A]
At t = 0, ![[A]=[A_o]](https://tex.z-dn.net/?f=%5BA%5D%3D%5BA_o%5D)
Initial rate = 0.0157 × 0.1108 = 
Therefore, the initial rate of the reaction is, 
An acid can be defined as a proton donor.
<u>Answer:</u> The edge length of the unit cell is 0.461 nm
<u>Explanation:</u>
We are given:
Atomic radius of iridium = 0.163 nm
To calculate the edge length, we use the relation between the radius and edge length for FCC lattice:

Putting values in above equation, we get:

Hence, the edge length of the unit cell is 0.461 nm
Answer:
[EtOH] = 2.2M and Wt% EtOH = 10.1% (w/w)
Explanation:
1. Molarity = moles solute / Volume solution in Liters
=> moles solute = mass solute / formula weight of solute = 9.8g/46g·mol⁻¹ = 0.213mol EtOH
=> volume of solution (assuming density of final solution is 1.0g/ml) ...
volume solution = 9.81gEtOH + 87.5gH₂O = 97.31g solution x 1g/ml = 97.31ml = 0.09731 Liter solution
Concentration (Molarity) = moles/Liters = 0.213mol/0.09731L = 2.2M in EtOH
2. Weight Percent EtOH in solution (assuming density of final solution is 1.0g/ml)
From part 1 => [EtOH] = 2.2M in EtOH = 2.2moles EtOH/1.0L soln
= {(2.2mol)(46g/mol)]/1000g soln] x 100% = 10.1% (w/w) in EtOH.
Molar mass of ( NH₄)₃PO₄ = 14.01×3 + 1.01×12 + 30.97 + 16.00×4 = 149.12 g/mol. Mass of 0.183 mol ...